大井研究室 Publications Prof.Ooi

依頼・招待講演 : Invited Lectures

112

「Molecular design of organic ions for asymmetric catalysis」

Advances in Organocatalysis, 2019/2/25, UK
111

「ハイブリッド触媒系による立体分岐型不斉合成」

第3回「ハイブリッド触媒」リトリート, 2019/1/26~1/27, 仙台
110

「Molecular Design and Asymmetric Catalysis of Weakly-Coordinating Chiral Anions」

International Conference on Organometallics and Catalysis, 2018/12/13~12/16, India
109

「Molecular Design and Asymmetric Catalysis of Weakly-Coordinating Chiral Anions」

6th Japan-UK Symposium on Asymmetric Catalysis, 2018/11/27~11/30, 福岡
108

「有機イオン対触媒の設計と機能創出」

2017年度有機合成化学協会・企業冠賞受賞講演(第一三共・創薬有機化学賞) 第114回有機合成シンポジウム, 2018/11/7, 東京
107

「分子を創り、振舞いを理解する:触媒機能から生物活性まで」

第44回反応と合成の進歩シンポジウム, 2018/11/5~11/6, 熊本
106

「新しい分子の振舞いを理解する:触媒機能から生物活性まで」

有機合成夏季セミナー, 2018/8/27~8/28, 大阪
105

「Molecular Design of Organic Ion Pairs for Asymmetric Catalysis」

ICCC 2018: Post Conference in Nagasaki, 2018/8/6, 長崎
104

「The Second Japanese-Spanish Symposium on Organic Synthesis」

The Second Japanese-Spanish Symposium on Organic Synthesis, 2018/5/28~5/29, 京都
103

「Molecular Design of Organic Ion Pairs for Asymmetric Catalysis」

Chinese Chemical Society Chemistry Congress , 2018/5/6~5/8, China
102

「新しい分子の振舞いを理解する:触媒機能から生物活性まで」

第32回農薬デザイン研究会 , 2017/11/17, 東京
101

「Molecular Design of Organic Ion Pairs for Asymmetric Catalysis」

1st International Symposium on Catalysis for Sustainable Chemical Synthesis , 2017/9/25~9/26, Freiburg, Germany
100

「ハイブリッド触媒系による立体分岐型不斉合成」

新学術領域研究キックオフシンポジウム , 2017/9/14, 東京
99

「Desiner Organic Ion-Pair Catalysis」

The 8th International Meeting on Halogen Chemistry , 2017/9/12~9/15, 犬山
98

「Catalyst-directed Multiple Selectivity Control」

Joint Symposium on. New Frontiers by Fusing Chemistry and Biology , 2017/7/13~7/14, Taiwan
97

「Catalyst-directed Multiple Selectivity Control」

The Japanese-Spanish Symposium on Modern Synthetic Methodology , 2017/4/24~4/26, Gijón, Spain
96

「Molecular Design of Organic Ion Pairs for Asymmetric Catalysis」

University of California, Berkeley, 2017/4/3, CA, USA
95

「α-ヘテロカルボニル化合物の触媒的不斉合成」

日本化学会第97春季年会特別企画「精密設計反応場を利用した高難度変換反応の開発」, 2017年03月19日, 横浜
94

"Behavior of Molecules: From Catalysis to Biological Functions;

The 3rd CSRS-ITbM Joint Workshop, 2017/01/12, Nagoya
93

「有機イオン触媒の設計と合成化学への応用」

平成28年度 後期(秋季)有機合成化学講習会, 2016年11月17日, 東京
92

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs;

International Symposium on Catalysis and Fine Chemicals 2016, 2016/11/10~11/14, Taipei
91

「イオン性触媒を活かしたものづくり」

金沢大学薬学シンポジウム「有機化学の先進的ビジョン」, 2016年10月17日, 金沢
90

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis;

JCO 2016 Journees de Chimie Organique, 2016/09/07~09/09, Paris
89

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis;

Institut de Chimie des Substances Naturelles, ICSN, 2016/09/06, Paris
88

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis;

Basler Chemische Gesellschaft Lecture, University of Basel, 2016/09/05, Basel
87

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis;

Columbia University, 2016/05/13, New York
86

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis;

Princeton University, 2016/05/12, New Jersey
85

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis;

Rutgers University, 2016/05/11, New Jersey
84

"Toward Catalytic Control of Photo-induced Radical Reactions;

Pre-symposium of IUPAC Photochemistry, 2016/04/01~04/02, Hiroshima
83

「基本反応活性種の触媒的制御を目指して」

日本化学会第96春季年会コラボレーション企画「未来を創る有機分子触媒」, 2016年03月26日, 京田辺
82

"Toward Catalytic Control of Photoinduced Radical Reactions"

The First Symposium of Chiral Molecular Science and Technology 2016, 2016/02/29~03/01, Chiba
81

"Design and Synthetic Applications of Organic Molecular Catalysts"

Recent Trends in Organocatalysis (#122), The International Chemical Congress of Pacific Basin Societies 2015, 2015/12/18, Honolulu, USA
80

"Ion-Paired Chiral Ligands for Asymmetric Transition-metal Catalysis"

Interplay between Theory and Experiment in Catalytic Research (#277), The International Chemical Congress of Pacific Basin Societies 2015, 2015/12/16, Honolulu, USA
79

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis"

大塚有機合成シンポジウム2015, 2015年11月19~21日, 船橋
78

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

Perspectives on Synthetic Chemistry Series 1, 2015/09/27~10/01, Singapore
77

「イオン性触媒を活かしたものづくり」

テクノ・フェア名大2015名大発・技術移転の萌芽, 2015年09月04日, 名古屋
76

「有機イオン対の分子設計に基づく触媒機能の創出と応用」

有機合成化学協会東海支部平成27年度有機合成セミナー, 2015年07月27日, 豊橋
75

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

39th Naito Conference: The Chemistry of Organocatalysts, 2015/07/06~07/09, Sapporo
74

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

16th Tetrahedron Symposium: Challenges in Bioorganic and Organic Chemistry, 2015/06/16~06/19, Berlin, Germany
73

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis"

The 3rd International Symposium on Transformative Bio-Molecules (ISTbM-3), 2015/5/25~5/26, Nagoya
72

「有機イオン対の分子設計に基づく触媒機能の創出と応用」

日本化学会第95春季年会特別企画「分子空間化学に基づいた精密有機合成と機能性材料の創製 」, 2015年03月29日, 船橋
71

「真の自在化学変換を担う分子技術の創出」

日本化学会第95春季年会中長期テーマシンポジウム「分子設計と分子技術:環境・資源・安全安心のための分子技術」, 2015年03月27日, 船橋
70

「有機イオン対の分子設計に基づく触媒機能の創出と応用」

山口大学応用分子生命科学常盤台コロキアム, 2015年02月24日, 宇部
69

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

KAUST Research Conferences: Catalytic Carbon and Hydrogen Management (KRC-CCHM), 2015/02/01~04, Thuwal, KSA
68

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis"

University of Pittsburgh, 2014/11/13, Pittsburgh, PA, USA
67

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

Vietnam Malaysia International Chemical Congress (VMICC) 2014, 2014/11/07~11/10, Hanoi, Vietnam
66

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

Ischia Advanced School of Organic Chemistry, 2014/09/21~09/25, Ischia, Naples, Italy
65

"Catalytic Control of Anionic Intermediates by Chiral Organic Cations"

Gordon Research Conference on Stereochemistry, 2014/07/27~08/01, Salve Regina University, Newport, RI, USA
64

"Ion-Pairing in Ligand Design for Asymmetric Transition-Metal Catalysis"

Gordon Research Conference (GRC) on Organic Reactions and Processes, 2014/07/13~18, Bryant University, Smithfield, RI, USA
63

"Unique Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

19th INTERNATIONAL SYMPOSIUM ON HOMOGENEOUS CATALYSIS, 2014/07/06~11, Ottawa
62

"Molecular Design and Synthetic Application of Chiral 1,2,3-Triazoliums"

97th Canadian Chemistry Conference and Exhibition, 2014/06/01~05, Vancouver
61

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

ICIQ Seminer, 2013/12/04, Tarragona
60

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

Monday Colloquium Lecturer, 2013/12/02, Zürich
59

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

John van Geuns Lecture, 2013/11/20, Amsterdam
58

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

Beijing Symposium 2013 on New Frontiers in Organic Chemistry: New Reagents, New Reactions, 2013/10/09-10, Beijing
57

「キラルオニウム塩の分子設計に基づく触媒機能の創出と応用」

第30回有機合成化学セミナー, 2013年09月17-19日, 岡山
56

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

Frontiers in Chemistry Armenia 2013, 2013/08/25-29, Yerevan, Armenia
55

「有機イオン対の分子設計に基づく触媒機能の創出と応用」

25周年記念 万有札幌シンポジウム 未来を拓く創造有機化学, 2013年06月06日, 札幌
54

"Ion-Paired Chiral Ligands for Asymmetric Palladium Catalysis"

Modern Trends in Organometallic Chemistry and Catalysis, 2013/06/03-07, Moscow
53

"Asymmetric Catalysis with Designer Chiral Organic Ion Pairs"

International Symposium on Frontiers in Molecular Catalysis 2013, 2013/04/26, Beijing
52

"Ion-Paired Chiral Ligands for Asymmetric Palladium Catalysis"

4th UK/Japan Conference in Catalytic Asymmetric Synthesis, 2013/04/19-20, Sendai
51

"Asymmetric Catalysis of Designer Chiral Organic Ion Pairs"

2012 IGER-RCMS International Nagoya Symposium on Transformative Synthesis, 2013/01/09, Nagoya
50

"Asymmetric Catalysis of Chiral 1,2,3-Triazolium Salts"

1st Japan-USA Organocatalytic Symposium in Hawaii (2012), 2012/12/16-18, Hawaii
49

「アニオン認識を鍵とする有機カチオンの分子設計と応用」

日本化学会関東支部 講演会「進化する有機分子触媒−その最先端と展望−」, 2012年08月31日, 東京
48

"Chiral Ammonium Betaines as an Ionic Nucleophilic Catalyst"

The 2nd International Conference on Molecular and Functional Catalysis (ICMFC-2), 2012/07/30-31, Singapore
47

「有機イオン対の分子設計に基づく触媒機能の創出と応用」

大阪府立大学 有機化学研究会 白鷺セミナー 第64回講演会, 2012年06月22日, 大阪
46

"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis"

The 47th Bürgenstock Conference, 2012/04/29-05/04, Brunnen, Switzerland
45

"Ion-Paired Chiral Ligands for Asymmetric Palladium Catalysis"

The 11th Anglo-Norman Organic Chemistry Colloquium (ANORCQ IX), 2012/04/15-04/17, Caen, France
44

"Ion-Paired Chiral Ligands for Asymmetric Palladium Catalysis"

1st Campus Asia Symposium 2012, 2011/03/12, Nagoya
43

"Ion-Paired Chiral Ligands for Asymmetric Palladium Cataiysis"

International Symposium on Catalysis and Fine Chemicals 2011, 2011/12/04-12/08, Nara
42

"Development of Chiral Arylaminophosphonium Barfates as a Charged Brønsted Acid Catalyst"

The First Germany-Japan Organocatalytic Symposium, 2011/10/14-10/15, Kyoto
41

"Ion-Paired Modular Chiral Ligands for Asymmetric Palladium Catalysis"

The 14th Asian Chemical Congress 2011, 2011/09/06-09/08, Thailand
40

「有機イオン対の構造制御に基づく触媒機能の創出と応用」

有機合成夏期セミナー「明日の有機合成化学」, 2011年9月5日, 大阪
39

"Unique Asymmetric Catalysis of Supramolecularly Assembled Chiral Tetraaminophosphonium

Phenoxides"
Singapore-Japan NTU-JSPS Joint Seminar, 2011/07/31-08/04, Singapore
38

「アニオン認識型第四級キラルオニウムの創製と応用」

平成23年度若手研究者のためのセミナー, 2011年7月28日, 岐阜
37

"Molecular Design and Synthetic Applications of Chiral 1,2,3-Triazolium Salts"

Gordon Research Conference on Heterocyclic Compounds Salve Regina University,
2011/06/26-07/01, Newport, RI, USA
36

「キラル第四級オニウム塩の分子設計から生まれる触媒機能」

平成23年度前期(春季)有機合成化学講習会「わが国の有機合成の底力」
長井記念ホール, 2011年6月22-23日, 東京
35

"Design and Applications of Chiral Quaternary Onium Salts Featuring Anion -Recognition Ability"

The XII Spring Meeting of the Division of Synthetic Chemistry, Spa Hotel Rantasipi Laajavuori Jyv・
skyl・, 2011/06/07-08, Finland
34

"Molecular Design of Chiral Tetraaminophosphonium Salts and Their Unique Asymmetric Catalyses"

Syngenta Lecture, Syngenta Crop Protection, 2011/04/19, Stein, Switzerland
33

"Molecular Design and Synthetic Applications of Chiral Quaternary Oniums Featuring Anion-Recognition Ability"

Lecture at University of Basel, University of Basel, 2011/04/18, Basel, Switzerland
32

"Design and Synthetic Application of Chiral 1,2,3-Triazoliums as Cationic Organic Catalysts with Anion-Recognition Ability"

3rd UK/Japan Symposium on Catalytic Asymmetric Synthesis, Chemistry Research Laboratory,
Oxford University, April 13-16, 2011, 2011/04/13-16, UK
31

「自然に組み上がる触媒:その働きを操る」
文部科学省科学研究費 特定領域研究「協奏機能触媒」(終了研究領域)講演会
「私たちに役立つ触媒って何?」東工大蔵前会館, 2011年1月11日, 東京

30

"Chiral Ammonium Betaines as a Unique Organic Molecular Catalyst."

The 2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010),
Hilton Hawaiian Village, 2010/12/16-20, Honolulu, USA
29

「有機イオン対の構造制御に基づく触媒機能創出と応用」

第3回有機触媒シンポジウム, 東北大学片平キャンパス 片平さくらホール, 2010年9月22日, 仙台
28

"Unique Asymmetric Catalysis of Supramolecularly Assembled Chiral Tetraaminophosphonium Phenoxides"

International Symposium on Organocatalysis Muelheim an der Ruhr ISOμ 2010,
The Max-Planck-Institut für Kohlenforschung, 2010/07/14-17, Muelheim, Germany
27

"Molecular Design of Chiral Tetraaminophosphonium Salts and Their Unique Asymmetric Catalyses"

The International Symposia on Advancing the Chemical Sciences 1st (ISACS1), Challenges in
Organic Chemistry and Chemical Biology Fairmont San Francisco hotel, 2010/07/06-09,
San Francisco, USA
26

「アミノホスホニウム塩の分子設計に基づく酸・塩基触媒機能の創出と応用」

日本薬学会第130年会 一般シンポジウム「有機触媒研究の新展開」, 岡山大学, 2010年3月29日, 岡山
25

"Design of Chiral Tetraaminophosphonium Salts as an Organic Molecular Catalyst for Selective Chemical Synthesis"

ACP Lecturship Award 2008 Tour in Taiwan, 2009/12/13-17, Taiwan
24

"Design of Chiral Tetraaminophosphonium Salts and Their Unique Asymmetric Catalyses"

The 4th International Symposium for Young Elements Chemists, 2009 Workshop on
Organometallic Chemistry, 九州大学筑紫キャンパス C-Cube, 2009年10月28-29日, 福岡
23

"Molecular Design and Synthetic Applications of Chiral Tetraaminophosphonium Salts"

第19回光学活性化合物シンポジウム, 日本薬学会館長井記念ホール, 2009年10月23日, 東京
22

「アミノホスホニウム塩の分子設計に基づく触媒機能創出と応用」

理研シンポジウム 第4回 「有機合成化学のフロンティア」, 理化学研究所, 2009年7月3日, 和光
21

「機能性イオン対協奏作用型有機分子触媒系の構築と応用」

文部科学省科学研究費補助金特定領域研究「協奏機能触媒」第6回公開シンポジウム,
東京大学武田先端知ビル, 2009年4月24〜25日, 東京
20

"Toward Asymmetric Synthesis of Oligopeptides Site-Specifically Incorporating Chiral α,α-Dialkyl-α-Amino Acid Residues"

UK/Japan Symposium on Asymmetric Catalysis, Kyoto University Clock Tower Centennial Hall ,
2008年12月8〜9日, 京都
19

「新規基質認識型キラル有機強塩基触媒の創製と応用」

文部科学省科学研究費補助金特定領域研究「炭素資源の高度分子変換」第6回公開シンポジウム,
石川県立音楽堂邦楽ホール , 2008年12月4〜5日, 金沢
18

"Molecular Design and Synthetic Utilities of Chiral Organic Ion Pair Catalysts"

5th Annual Japanese-German Frontiers of Science Symposium, Atrium Hotel Mainz,
2008/10/31〜11/2, Germany
17

「アミノホスホニウム塩の分子設計に基づく触媒機能創出と不斉合成への活用」

北海道大学グローバルCOEシンポジウム「触媒的不斉合成の最先端」, 北海道大学,
2008年10月24〜25日, 札幌
16

"Chiral Ammonium Betaines: Design and Application as an Enantioselective Orgainc Base Catalyst"

3rd International Conference on Cutting-Edge Organic Chemistry in Asia under Asian Core Program
(ICCEOA-3), Zhejiang University , 2008/10/19〜23, China
15

"Molecular Design and Synthetic Applications of Chiral Tetraaminophosphonium Salts"

1st Japan-Singapore Bilateral Symposium on Catalysis, National University of Singapore,
2008/01/06〜09, Singapore
14

"Molecular Design and Synthetic Applications of Chiral Tetraaminophosphonium Salts"

4th Japanese-Sino Symposium on Organic Chemistry for Young Scientists, ヒルトン成田,
2007年9月22〜26日, 名古屋
13

「キラルオニウム塩の分子設計に基づく触媒的不斉合成」

2007年度ファインケミカルズ合成触媒研究会シンポジウム, 名古屋大学ベンチャービジネスラボラトリ,
2007年6月4日, 名古屋
12

「キラルオニウム塩の分子設計に基づく実践的不斉合成」

有機合成化学協会九州山口支部 平成20年度 有機合成化学講演会「合成有機化学のフロンティア」,
九州大学創立五十周年記念講堂, 2007年5月11日, 福岡
11

"Development of Phase-Transfer-Catalyzed Asymmetric Strecker Reaction Based on the Molecular Design of Chiral Quaternary Ammonium Salts"

American Chemical Society 233rd National Meeting, The McCormick Place Convention Center,
2007, 3, 25, Chicago, USA
10

「相間移動触媒作用を活かした実用的不斉合成」

近畿化学協会有機金属部会平成18年度第4回例会, 大阪科学技術センター ,
2007年2月1日, 大阪
9

「キラルアンモニウム塩の分子設計に基づく二相系での不斉ストレッカ-反応の開発」

名古屋大学 21 世紀 COE プログラム「物質科学の拠点形成:分子機能の解明と創造」
第3回 有機化学若手研究会, 名古屋大学東山キャンパス 野依記念物質科学研究館,
2006年12月1-2日, 名古屋
8

「不斉炭素-炭素結合形成」

実力養成化学スクール:第4回「キラル化学-不斉合成」研修コース, 化学会館, 2006年8月4-5日, 東京
7

“Selective Structural Reorganization of Amino Carbonyl Compounds through Organoaluminum-Mediated 1,2-Rearrangement”
The 2005 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2005),
Hilton Hawaiian Village, 2005/12/15-20, Honolulu, USA

6

「キラルアンモニウム塩の分子設計を基盤とする実用的不斉合成プロセスの開拓」

北海道大学触媒化学研究センター研究討論会「明日を創る有機化学」, 北海道大学学術交流会館,
2004年11月11-12日, 札幌
5

「光学活性アンモニウムビフルオリドのデザインを機軸とする触媒的不斉合成」

有機フッ素化学セミナー「含フッ素リガンドの展開」, 岡山大学ベンチャービジネスラボラトリー,
2004年8月27日, 岡山
4

「N-スピロ型光学活性相間移動触媒の創製と実用的アミノ酸合成への応用」

21COE京都大学化学連携研究教育拠点「有機元素化学セミナー」, 京都大学化学研究所,
2004年1月19日, 宇治
3

「二点配位型アルミニウム触媒の創製と精密合成への応用」

特定領域研究「集積型金属錯体」主催「錯体化学の未来シンポジウム」, ぱるるプラザ京都,
2000年2月11-12日, 京都
2

「精密分子認識を指向した二点配位型ルイス酸の創製と応用」

日本化学会第76春季年会, 神奈川大学, 1999年3月28-31日, 横浜
1

「二点配位型アルミニウム反応剤の創製と合成化学的展開」

有機合成化学協会東北北海道支部主催「若手研究者のための有機化学札幌セミナー」,
北海道大学学術交流会館, 1998年7月17日, 札幌
ページの先頭へ

原著論文 : Oridinal Papers

183.

Photocatalytic Borylcyclopropanation of α-Boryl Styrenes

Tsuyoshi Ohtani, Yuto Tsuchiya, Daisuke Uraguchi and Takashi Ooi

Org. Chem. Front. 2019, xx, xxx-xxx

DOI: 10.1039/c9qo00197b

182.

A femto-molar range suicide germination stimulant for the parasitic plant Striga hermonthica

Daisuke Uraguchi, Keiko Kuwata, Yuh Hijikata, Rie Yamaguchi, Hanae Imaizumi, Sathiyanarayanan AM, Christin Rakers, Narumi Mori, Kohki Akiyama, Stephan Irle, Peter McCourt, Toshinori Kinoshita, Takashi Ooi, Yuichiro Tsuchiya

Science 2018, 362, 1301-1305

DOI: 10.1126/science.aau5445

181.

Catalyst-Directed Guidance of Sulfur-Substituted Enediolates to Stereoselective Carbon-Carbon Bond Formation with Aldehydes

Daisuke Uraguchi, Kohei Yamada, Makoto Sato, and Takashi Ooi

J. Am. Chem. Soc. 2018, 140, 5110-5117

DOI: 10.1021/jacs.7b12949

180.

Catalyst-Enabled Site-divergent Stereoselective Michael Reactions: Overriding Intrinsic Reactivity of Enynyl Carbonyl Acceptors

Daisuke Uraguchi, Ryo Shibazaki, Naoya Tanaka, Kohei Yamada, Ken Yoshioka, and Takashi Ooi

Angew. Chem. Int. Ed. 2018, 57, 4732-4736

DOI: 10.1002/anie.201800057

179.

Allenedicarboxylate as a Stereochemically Labile Electrophile for Chiral Organic Base-Catalyzed Stereoselective Michael Addition

Daisuke Uraguchi, Yasutaka Kawai, Hitoshi Sasaki, Kohei Yamada, and Takashi Ooi

Chem. Lett. 2018, 47, 594-597

DOI: 10.1246/cl.180031

178.

Molecular Design, Synthesis, and Asymmetric Catalysis of a Hexacoordinated Chiral Phosphate Ion

Daisuke Uraguchi, Hitoshi Sasaki, Yuto Kimura, Takaki Ito, and Takashi Ooi

J. Am. Chem. Soc. 2018, 140, 2765-2768

DOI: 10.1021/jacs.7b13433

177.

Diastereo- and enantioselective phase-transfer alkylation of 3-substituted oxindoles with racemic secondary alkyl halides

Kohsuke Ohmatsu, Yukino Furukawa, Mari Kiyokawa and Takashi Ooi

Chem. Commun. 2017, 53, 13113-13116

DOI: 10.1039/C7CC07122A

176.

Photoredox Ketone Catalysis for Direct C-H Imidation and Acyloxylation of Arenes

Chandra Bhushan Tripathi, Tsuyoshi Ohtani, Michael T. Corbett and Takashi Ooi

Chem. Sci. 2017, 8, 5622-5627

DOI: 10.1039/C7SC01700F

175.

Determination of the absolute configuration of compounds bearing chiral quaternary carbon centers using the crystalline sponge method

Shiho Sairenji, Takashi Kikuchi, Mohamed Ahmed Abozeid, Shinobu Takizawa, Hiroaki Sasai, Yuichiro Ando, Kohsuke Ohmatsu, Takashi Ooi and Makoto Fujita

Chem. Sci. 2017, 8, 5132-5136

DOI: 10.1039/c7sc01524k

174.

N-Sulfonyl α-Imino Ester-Derived Chiral Oxaziridines: Catalytic Asymmetric Synthesis and Application as a Modular Chiral Organic Oxidant

Naoya Tanaka, Ryosuke Tsutsumi, Daisuke Uraguchi,Takashi Ooi

Chem. Commun. 2017, 53, 6999-7002

DOI: 10.1039/C7CC02502E

173.

Unique Site-selectivity Control in Asymmetric Michael Addition of Azlactone to Alkenyl Dienyl Ketones Enabled by P-Spiro Chiral Iminophosphorane Catalysis

Ken Yoshioka, Kohei Yamada, Daisuke Uraguchi,Takashi Ooi

Chem. Commun. 2017, 53, 5495-5498

DOI: 10.1039/C7CC01715D

172.

Acridinium Betaine as a Single-Electron-Transfer Catalyst: Design and Application to Dimerization of Oxindoles

Daisuke Uraguchi, Masahiro Torii, Takashi Ooi

ACS Catal. 2017, 7, 2765-2769

DOI: 10.1021/acscatal.7b00265

171.

Complete diastereodivergence in asymmetric 1,6-addition reactions enabled by minimal modification of a chiral catalyst

Daisuke Uraguchi, Ken Yoshioka, Takashi Ooi

Nature Communications 2017, 8, 14793

DOI: 10.1038/ncomms14793

170.

[5.5]-P-Spirocyclic Chiral Triaminoiminophosphorane-Catalyzed Asymmetric Hydrophosphonylation of Aldehydes and Ynones

Daisuke Uraguchi, Takaki Ito, Yuto Kimura, Yumiko Nobori, Makoto Sato, Takashi Ooi

Bull. Chem. Soc. Jpn. 2017, 90, 546-555

DOI: 10.1246/bcsj.20170040

169.

In Situ Electrophilic Activation of Hydrogen Peroxide for Catalytic Asymmetric α-Hydroxylation of 3-Substituted Oxindoles

Kohsuke Ohmatsu, Yuichiro Ando, Takashi Ooi

Synlett 2017, xx, xxx-xxx

DOI: 10.1055/s-0036-1558958

168.

Stereoselective Aza-Henry Reaction of 3-Nitro-Dihydro-2(1H)-Quinolones with N-BOC-Aldimines under the Catalysis of Chiral Ammonium Betaines

Daisuke Uraguchi, Masahiro Torii, Kohsuke Kato, Takashi Ooi

Heterocycles 2017, 94, 441-447

DOI: 10.3987/COM-16-13642

167.

A Modular Strategy for the Direct Catalytic Asymmetric α-Amination of Carbonyl Compounds

Kohsuke Ohmatsu, Yuichiro Ando, Tsubasa Nakashima, Takashi Ooi

Chem 2016, 1, 802-810

DOI: 10.1016/j.chempr.2016.10.012

166.

Origin of High Regio-, Diastereo-, and Enantioselectivities in 1,6-Addition of Azlactones to Dienyl N-Acylpyrroles: A Computational Study

Yamanaka, Masahiro; Sakata, Ken; Yoshioka, Ken; Uraguchi, Daisuke; Ooi, Takashi

J. Org. Chem. 2017, 82, 541-548

DOI: 10.1021/acs.joc.6b02572

165.

Chiral Ammonium Betaine-Catalyzed Asymmetric Mannich-Type Reaction of Oxindoles

Masahiro Torii, Kohsuke Kato, Daisuke Uraguchi, and Takashi Ooi

Beilstein J. Org. Chem. 2016, 12, 2099-2103

DOI: 10.3762/bjoc.12.199

164.

Independence from the Sequence of Single-Electron Transfer of Photoredox Process in Redox-Neutral Asymmetric Bond-Forming Reaction

Tomohito Kizu, Daisuke Uraguchi, and Takashi Ooi

J. Org. Chem. 2016, 81, 6953-6958

DOI: 10.1021/acs.joc.6b00445

163.

Multiple Absolute Stereocontrol in Pd-Catalyzed [3+2] Cycloaddition of Oxazolidinones and Trisubstituted Alkenes Using Chiral Ammonium-Phosphine Hybrid Ligands

Naomichi Imagawa, Yuya Nagato, Kohsuke Ohmatsu, and Takashi Ooi

Bull. Chem. Soc. Jpn. 2016, 89, 649-656

DOI: 10.1246/bcsj.20160053

162.

Anion-Stoichiometry-Dependent Selectivity Enhancement in Ion-Paired Chiral Ligand-Palladium Complex Catalyzed Enantioselective Allylic Alkylation

Kohsuke Ohmatsu, Yoshiyuki Hara, Yuya Kusano, Takashi Ooi

Synlett 2016, 27, 1047-1050

DOI: 10.1055/s-0035-1561403

161.

Palladium-Catalyzed Branch-Selective Decarboxylative Allylation Using Ion-Paired Ligands

Yoshiyuki Hara, Yuya Kusano, Kohsuke Ohmatsu, and Takashi Ooi

Chem. Lett. 2016, 45, 552-554

DOI: 10.1246/cl.160158

160.

Synergistic Catalysis of Ionic Brønsted Acid and Photosensitizer for a Redox Neutral Asymmetric α-Coupling of N-Arylaminomethanes with Aldimines

Daisuke Uraguchi, Natsuko Kinoshita, Tomohito Kizu, and Takashi Ooi

J. Am. Chem. Soc. 2015, 137, 13768-13771

DOI: 10.1021/jacs.5b09329

159.

Enantioselective Reductive Multicomponent Coupling Reactions between Isatins and Aldehydes

Matthew A. Horwitz, Naoya Tanaka, Takuya Yokosaka, Daisuke Uraguchi, Jeffrey S. Johnson, and Takashi Ooi

Chem. Sci. 2015, 6, 6086-6090

DOI: 10.1039/C5SC02170G

158.

Catalytic Asymmetric Cyanation of Alkylideneindolenines Generated from Sulfonylalkylindoles

Kohsuke Ohmatsu, Yukino Furukawa, Daigo Nakaguro, and Takashi Ooi

Chem. Lett. 2015, 44, 1350-1352

DOI: 10.1246/cl.150581

157.

Highly E- and Enantioselective Michael Addition to Electron-deficient Internal Alkynes under the Catalysis of Chiral Iminophosphorane

Daisuke Uraguchi, Kohei Yamada, Takashi Ooi

Angew. Chem. Int. Ed. 2015, 54, 9954-9957

DOI: 10.1002/anie.201503928

156.

Vinylogy in Nitronates: Utilization of α-Aryl Conjugated Nitroolefins as a Nucleophile for Highly Stereoselective Aza-Henry Reaction

Keigo Oyaizu, Daisuke Uraguchi, Takashi Ooi

Chem. Commun. 2015, 51, 4437-4439

DOI: 10.1039/C4CC10261D

155.

Palladium-Catalyzed Asymmetric [3 + 2] Cycloaddition of 5-Vinyloxazolidinones with Imines Using Chiral Ammonium-Phosphine Hybrid Ligand

Kohsuke Ohmatsu, Shinya Kawai, Naomichi Imagawa, Takashi Ooi

ACS Catal. 2014, 4, 4304-4306

DOI: 10.1021/cs501369z

154.

Chiral Ammonium Betaine-Catalyzed Highly Stereoselective Aza-Henry Reaction of α-Aryl Nitromethanes with Aromatic N-Boc Imines

Daisuke Uraguchi, Keigo Oyaizu, Haruhiro Noguchi, Takashi Ooi

Chem. Asian J. 2014, 10, 334-337

DOI: 10.1002/asia.201402943

153.

Enantioselective Protonation of α-Hetero Carboxylic Acid-Derived Ketene Disilyl Acetals under Chiral Ionic Brønsted Acid Catalysis

Daisuke Uraguchi, Tomohito Kizu, Yuki Ohira, Takashi Ooi

Chem. Commun. 2014, 50,13489-13491

DOI: 10.1039/C4CC06081D

152.

In-Situ Generation of Ion-Paired Chiral Ligands: Rapid Identification of Optimal Ligand for Palladium-Catalyzed Asymmetric Allylation

Kohsuke Ohmatsu, Yoshiyuki Hara, Takashi Ooi

Chem. Sci. 2014, 5, 3645-3650

DOI: 10.1039/C4SC01032A

151.

Enantioselective formal α-allylation of nitroalkanes through a chiral iminophosphorane-catalyzed Michael reaction-Julia-Kocienski olefination sequence

Daisuke Uraguchi, Shinji Nakamura, Hitoshi Sasaki, Yuki Konakade, Takashi Ooi

Chem. Commun. 2014, 50, 3491-3493

DOI: 10.1039/C3CC49477B

150.

Practical Preparation of Chiral N-Sulfonyl Oxaziridines by Catalytic Asymmetric Payne Oxidation

Ryosuke Tsutsumi, Seonwoo Kim, Daisuke Uraguchi, Takashi Ooi

Synthesis (PSP article) 2014, 46, 871-878

DOI: 10.1055/s-0033-1340818

149.

Ligand-controlled E/Z selectivity and enantioselectivity in palladium-catalyzed allylation of benzofuranones with 1,2-disubstituted allylic carbonates

Kohsuke Ohmatsu, Mitsunori Ito , Takashi Ooi

Chem. Commun. 2014, 50, 4554-4557

DOI: 10.1039/C3CC49338E

148.

Asymmetric Alkylation of α-Cyanosulfones Catalyzed by Chiral 1,2,3-Triazolium Salts

Kohsuke Ohmatsu, Yusuke Hakamata, Ayano Goto, Takashi Ooi

Heterocycles 2014, 88, 1661-1666

DOI: 10.3987/COM-13-S(S)121

147.

Catalytic asymmetric Payne oxidation under the catalysis of P-spiro chiral triaminoiminophosphorane: Application to the synthesis of N-sulfonyl oxaziridines

Daisuke Uraguchi, Ryosuke Tsutsumi, Takashi Ooi

Tetrahedron 2014, 70, 1691-1701

DOI: 10.1016/j.tet.2013.12.086

146.

Asymmetric Substitution at the Tetrasubstituted Chiral Carbon: Catalytic Ring-Opening Alkylation of Racemic 2,2-Disubstituted Aziridines with 3-Substituted Oxindoles

Kohsuke Ohmatsu, Yuichiro Ando , Takashi Ooi

J. Am. Chem. Soc. 2013, 135, 18706-18709

DOI: 10.1021/ja411647x

145.

Ligand-enabled multiple absolute stereocontrol in metal-catalysed cycloaddition for construction of contiguous all-carbon quaternary stereocenters

Kohsuke Ohmatsu, Naomichi Imagawa, Takashi Ooi

Nature Chem. 2014, 6, 47-51

DOI: 10.1038/nchem.1796

144.

Production at the Curie Level of No-Carrier-Added 6-18F-Fluoro-L-Dopa

Lionel C. Libert, Xavier Franci, Alain R. Plenevaux, Takashi Ooi, Keiji Maruoka, Andró J. Luxen, Christian F. Lemaire

J. Nucl. Med. 2013, 54, 1154-1161

DOI: 10.2967/jnumed.112.112284

143.

Carbene Transfer from Triazolylidene Gold Complexes as a Potent Strategy for Inducing High Catalytic Activity

Daniel Canseco-Gonzalez, Ana Petronilho, Helge Mueller-Bunz, Kohsuke Ohmatsu, Takashi Ooi, Martin Albrecht

J. Am. Chem. Soc. 2013, 135, 13193-13203

DOI: 10.1021/ja406999p

142.

Catalytic Asymmetric Oxidation of N-Sulfonyl Imines with Hydrogen Peroxide−Trichloroacetonitrile System

Daisuke Uraguchi, Ryosuke Tsutsumi, and Takashi Ooi

J. Am. Chem. Soc. 2013, 135, 8161-8164

DOI: 10.1021/ja403491j

141.

Exploiting the Modularity of Ion-Paired Chiral Ligands for Palladium-Catalyzed Enantioselective Allylation of Benzofuran-2(3H)-ones

Kohsuke Ohmatsu, Mitsunori Ito, Tomoatsu Kunieda, and Takashi Ooi

J. Am. Chem. Soc. 2013, 135, 590−593

DOI: 10.1021/ja312125a

140.

Highly Stereoselective Michael Addition of Azlactones to Electron-Deficient Triple Bonds under P-Spiro Chiral Iminophosphorane Catalysis: Importance of Protonation Pathway

Uraguchi, Daisuke; Ueki, Yusuke; Sugiyama, Atsushi; Ooi, Takashi

Chem. Sci. 2013, 4, 1308-1311

DOI: 10.1039/C2SC22027J

139.

Highly Regio-, Diastereo-, and Enantioselective 1,6- and 1,8-Additions of Azlactones to Di- and Trienyl N-Acylpyrroles

Uraguchi, Daisuke; Yoshioka, Ken; Ueki, Yusuke; Ooi, Takashi

J. Am. Chem. Soc. 2012, 134, 19370-19373.

DOI: 10.1039/C2SC22027J

138.

Chiral Ionic Brønsted Acid-Achiral Brønsted Base Synergistic Catalysis for Asymmetric Sulfa-Michael Addition to Nitroolefins

Uraguchi, Daisuke; Kinoshita, Natsuko; Nakashima, Daisuke; Ooi, Takashi

Chem. Sci. 2012, 3, 3161-3164.

DOI: 10.1039/C2SC20698F

137.

Catalytic Asymmetric Ring Openings of Meso and Terminal Aziridines with Halides Mediated by Chiral 1,2,3-Triazolium Silicates

Ohmatsu, Kohsuke; Hamajima, Yuta; Ooi, Takashi

J. Am. Chem. Soc. 2012, 134, 8794-8797.

DOI: 10.1021/ja3028668

136.

Catalytic Asymmetric Mannich-Type Reactions of α-Cyano α-Sulfonyl Carbanions

Ohmatsu, Kohsuke; Goto, Ayano; Ooi, Takashi

Chem. Commun. 2012, 48, 7913-7915.

DOI: 10.1039/C2CC32398B

135.

Nitroolefins as a Nucleophilic Component for Highly Stereoselective Aza-Henry Reaction under the Catalysis of Chiral Ammonium Betaines

Uraguchi, Daisuke; Oyaizu, Keigo; Ooi, Takashi

Chem. Eur. J. 2012, 18, 8306-8309.

DOI: 10.1002/chem.201201259

134.

Ionic Nucleophilic Catalysis of Chiral Ammonium Betaines for Highly Stereoselective Aldol Reaction from Oxindole-Derived Vinylic Carbonates

Uraguchi, Daisuke; Koshimoto, Kyohei; Ooi, Takashi

J. Am. Chem. Soc. 2012, 134, 6972-6975.

DOI: 10.1021/ja3022939

133.

Ion-paired chiral ligands for asymmetric palladium catalysis

Ohmatsu, Kohsuke; Ito, Mitsunori; Kunieda, Tomoatsu; Ooi, Takashi

Nat. Chem. 2012, 4, 473-477.

DOI:10.1038/nchem.1311

132.

Base-Catalyzed Direct Aldolization of α-Alkyl-α-Hydroxy Trialkyl Phosphonoacetates

Corbett, Michael; Uraguchi, Daisuke; Ooi, Takashi; Johnson, Jeffrey

Angew. Chem. Int. Ed. 2012, 51, 4685-4689.

DOI: 10.1002/anie.201200559

131.

Highly Stereoselective Catalytic Conjugate Addition of Acyl Anion Equivalent to Nitroolefins

Uraguchi, Daisuke; Ueki, Yusuke; Ooi, Takashi

Chem. Sci. 2012, 3, 842-845.

DOI: 10.1039/C1SC00678A

130.

Enantioselective Aza-Michael Addition to Conjugated Nitroenynes Catalyzed by Chiral Arylaminophosphonium Barfates

Uraguchi, Daisuke; Kinoshita, Natsuko; Kizu, Tomohito; Ooi, Takashi

Synlett. 2011, 1265-1267.

DOI: 10.1055/s-0030-1260541

129.

Precise Control of Spontaneous Molecular Assembly of Chiral Tetraaminophosphonium Aryloxide−Arylhydroxide(s) in Solution

Uraguchi, Daisuke; Ueki, Yusuke; Ooi, Takashi

Angew. Chem. Int. Ed. 2011, 50, 3681-3683.

DOI: 10.1002/anie.201007752

128.

Chiral 1,2,3-Triazoliums as New Cationic Organic Catalysts with Anion-Recognition Ability: Application to Asymmetric Alkylation of Oxindoles

Ohmatsu, Kohsuke, Kiyokawa, Mari, Ooi, Takashi

J. Am. Chem. Soc. 2011, 133, 1307-1309.

DOI: 10.1021/ja1102844

127.

Catalytic Asymmetric Protonation of α-Amino Acid-Derived Ketene Disilyl Acetals Using P-Spiro Diaminodioxaphosphonium Barfates as Chiral Proton

Uraguchi, Daisuke; Kinoshita, Natsuko; Ooi, Takashi

J. Am. Chem. Soc. 2010, 132, 12240-12242.

DOI: 10.1021/ja105945z

126.

Catalytic Asymmetric Direct Henry Reaction of Ynals: Short Syntheses of (2S,3R)-(+)-Xestoaminol C and (−)-Codonopsinines

Uraguchi, Daisuke; Nakamura, Shinji; Ooi, Takashi

Angew. Chem. Int. Ed. 2010, 49, 7562-7565.

DOI: 10.1002/anie.201004072

125.

Chiral Ammonium Betaines as an Ionic Nucleophilic Catalyst

Uraguchi, Daisuke; Koshimoto, Kyohei; Miyake, Shuhei; Ooi, Takashi

Angew. Chem. Int. Ed. 2010, 49, 5567-5569.

DOI: 10.1002/anie.201002315

124.

Catalytic Asymmetric Hydrophosphonylation of Ynones

Uraguchi, Daisuke; Ito, Takaki; Nakamura, Shinji; Ooi, Takashi

Chem. Sci. 2010, 1, 488-490.

DOI: 10.1039/c0sc00268b

123.

Performance of C1-symmetric chiral ammonium betaines as a catalyst for the enantioselective Mannich-type reaction of α-nitrocarboxylates

Uraguchi, Daisuke; Koshimoto, Kyohei; Sanada, Chisato; Ooi, Takashi

Tetrahedron: Asymmetry. 2010, 21, 1189-1190.

http://dx.doi.org/10.1016/j.tetasy.2010.04.006

122.

Flexible Synthesis, Structural Determination, and Synthetic Application of a New C1-Symmetric Chiral Ammonium Betaine

Uraguchi, Daisuke; Koshimoto, Kyohei; Ooi, Takashi

Chem. Commun. 2010, 46, 300-302.

http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b916627k

121.

Phase-Transfer-Catalyzed Asymmetric Alkylation of α-Benzoyloxy-β-keto Esters: Stereoselective Construction of Congested 2,3-Dihydroxycarboxylic Acid Esters

Hashimoto, Takuya; Sasaki, Keigo; Fukumoto, Kazuhiro; Murase, Yuichi; Abe, Naoyuki; Ooi, Takashi; Maruoka, Keiji

Chem. Asian J. 2010, 5, in press.

http://www3.interscience.wiley.com/journal/123207901/abstract

120.

Diastereo- and Enantioselective Direct Henry Reaction of Pyruvates Mediated by Chiral P-Spiro Tetraaminophosphonium salts

Uraguchi, Daisuke; Ito, Takaki; Nakamura, Shinji; Sakaki, Sawako; Ooi, Takashi

Chem. Lett. 2009, 38, 1052.

http://www.jstage.jst.go.jp/article/cl/38/11/38_1052/_article

119.

Chiral Organic Ion Pair Catalysts Assembled Through a Hydrogen-Bonding Network

Uraguchi, Daisuke; Ueki, Yusuke; Ooi, Takashi

Science. 2009, 326, 120-123.

http://www.sciencemag.org/cgi/content/abstract/326/5949/120

118.

Al Lewis acid-catalyzed regiodivergent 1,2-rearrangement of α-siloxy aldehydes: scope and mechanism

Kohsuke Ohmatsu, Takayuki Tanaka, Takashi Ooi, Keiji Maruoka

Tetrahedron. 2009, 65, 7516-7522.

http://dx.doi.org/10.1016/j.tet.2009.06.126

117.

Chiral Arylaminophosphonium Barfates as a New Class of Charged Br?nsted Acid for the Enantioselective Activation of Nonionic Lewis Bases

Uraguchi, Daisuke; Nakashima, Daisuke; Ooi, Takashi

J. Am. Chem. Soc. 2009, 131, 7242-7243.

http://pubs.acs.org/doi/abs/10.1021/ja903271t

116.

Generation of Chiral Phosphonium Dialkyl Phosphite as a Highly Reactive P-Nucleophile: Application to Asymmetric Hydrophosphonylation of Aldehydes

Uraguchi, Daisuke; Ito, Takaki; Ooi, Takashi

J. Am. Chem. Soc. 2009, 131, 3836-3837.

http://pubs.acs.org/doi/abs/10.1021/ja810043d

115.

Phase-transfer-catalyzed Enantioselective Alkylation of α-Benzoyloxy-β-keto ester

Hashimoto, Takuya; Sasaki, Keigo; Fukumoto, Kazuhiro; Murase, Yuichi; Ooi, Takashi; Maruoka, Keiji

Synlett. 2009, 661-663.

http://www.thieme-connect.de/DOI/DOI?10.1055/s-0028-1087814

114.

Asymmetric Synthesis of α,α-Disubstituted-α-Amino Acids via Enantioselective Alkylation of Azlactones under Biphasic Conditions Using P-Spiro Chiral Tetraaminophosphonium Salts as a Phase-Transfer Catalyst

Uraguchi, Daisuke; Asai, Yoshihiro; Seto, Yuki; Ooi, Takashi

Synlett. 2009, 658-660.

http://www.thieme-connect.com/ejournals/abstract/synlett/doi/10.1055/s-0028-1087812

113.

Site-directed Asymmetric Quaternization of a Peptide Backbone at a C-Terminal Azlactone

Uraguchi, Daisuke; Asai, Yoshihiro; Ooi, Takashi

Angew. Chem. Int. Ed. 2009, 48, 733-737.

http://dx.doi.org/10.1002/anie.200803661

112.

Chiral Tetraaminophosphonium Carboxylate-Catalyzed Direct Mannich-Type Reaction

Uraguchi, Daisuke; Ueki, Yusuke; Ooi, Takashi

J. Am. Chem. Soc. 2008, 130, 14088-14089.

http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/asap/abs/ja806311e.html

111.

Chiral Ammonium Betaines: A Bifunctional Organic Base Catalyst for Asymmetric Mannich-type Reaction of α-Nitrocarboxylates

Uraguchi, Daisuke; Koshimoto, Kyohei; Ooi, Takashi

J. Am. Chem. Soc. 2008, 130, 10878-10879.

http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/asap/abs/ja8041004.html

110.

Synthesis of Chiral Tetraaminophosphonium Chlorides from N-BOC α-Amino Acid Esters

Uraguchi, Daisuke; Sakaki, Sawako; Ueki, Yusuke; Ito, Takaki; Ooi, Takashi

Heterocycles. 2008, 76, 1081-1085.

http://www.heterocycles.jp/library/abstract.php?article=3158

109.

Complete Switch of Migratory Aptitude in Aluminum-Catalyzed 1,2-Rearrangement of Differently a,a-Disubstituted a-Siloxy Aldehydes

Ohmatsu, Kohsuke; Tanaka, Takayuki; Ooi, Takashi; Maruoka, Keiji

Angew. Chem. Int. Ed. 2008, 47, 5203-5206.

http://dx.doi.org/10.1002/anie.200800801

108.

Chiral Tetraaminophosphonium Salt-Mediated Asymmetric Direct Henry Reaction

Uraguchi, Daisuke; Sakaki, Sawako; Ooi, Takashi

J. Am. Chem. Soc. 2007, 129, 12392-12393.

http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2007/129/i41/abs/ja075152+.html

107.

Practical Stereoselective Synthesis of β-Branched α-Amino Acids through Efficient Kinetic Resolution in the Phase-Transfer-Catalyzed Asymmetric Alkylations

Ooi, Takashi; Kato, Daisuke; Inamura, Koji; Ohmatsu, Kohsuke; Maruoka, Keiji

Org. Lett. 2007, 9, 3945-3948.

http://dx.doi.org/10.1021/ol701558e

106.

Catalytic Asymmetric Rearrangement of α,α-Disubstituted α-Siloxy Aldehydes to Optically Active Acyloins Using Axially Chiral Organoaluminum Lewis Acids

Ooi, Takashi; Ohmatsu, Kohsuke; Maruoka, Keiji

J. Am. Chem. Soc. 2007, 129, 2410-2411.

http://dx.doi.org/10.1021/ja063051q

105.

Advantage of in situ generation of N-arylsulfonyl imines from α-amide sulfones in the phase-transfer-catalyzed asymmetric Strecker reaction

Ooi, Takashi; Uematsu, Yukitaka; Fujimoto, Jun; Fukumoto, Kazuhiro; Maruoka, Keiji

Tetrahedron Lett. 2007, 48, 1337-1340.

http://dx.doi.org/10.1016/j.tetlet.2006.12.122

104.

Highly diastereo- and enantioselective formal conjugate addition of nitroalkanes to nitroalkenes by chiral ammonium bifluoride catalysis

Ooi, Takashi; Takada, Saki; Doda, Kanae; Maruoka, Keiji

Angew. Chem., Int. Ed. 2006, 45, 7606-7608.

http://dx.doi.org/10.1002/anie.200602787

103.

Asymmetric phase-transfer catalysis of homo- and heterochiral quaternary ammonium salts: development and application of conformationally flexible chiral phase-transfer catalysts

Ooi, Takashi; Uematsu, Yukitaka; Kameda, Minoru; Maruoka, Keiji

Tetrahedron. 2006, 62, 11425-11436.

http://dx.doi.org/10.1016/j.tet.2006.08.052

102.

Asymmetric synthesis of α-acyl-γ-butyrolactones possessing all-carbon quaternary stereocenters by phase-transfer-catalyzed alkylation.

Ooi, Takashi; Miki, Takashi; Fukumoto, Kazuhiro; Maruoka, Keiji

Adv. Synth. Catal. 2006, 348, 1539-1542.

http://dx.doi.org/10.1002/adsc.200606064

101.

Construction of Enantiomerically Enriched Tertiary α-Hydroxycarboxylic Acid Derivatives by Phase-Transfer-Catalyzed Asymmetric Alkylation of Diaryloxazolidin-2,4-diones

Ooi, Takashi; Fukumoto, Kazuhiro; Maruoka, Keiji

Angew. Chem., Int. Ed. 2006, 45, 3839-3842.

http://dx.doi.org/10.1002/anie.200600470

100.

Highly enantioselective monoalkylation of p-chlorobenzaldehyde imine of glycine tert-butyl ester under mild phase-transfer conditions

Ooi, Takashi; Arimura, Yuichiro; Hiraiwa, Yukihiro; Yuan, Lin Ming; Kano, Taichi; Inoue, Toru; Matsumoto, Jun; Maruoka, Keiji

Tetrahedron: Asym. 2006, 17, 603-606.

http://dx.doi.org/10.1016/j.tetasy.2006.01.019

99.

Asymmetric Strecker Reaction of Aldimines Using Aqueous Potassium Cyanide by Phase-Transfer Catalysis of Chiral Quaternary Ammonium Salts with a Tetranaphthyl Backbone

Ooi, Takashi; Uematsu, Yukitaka; Maruoka, Keiji

J. Am. Chem. Soc. 2006, 128, 2548-2549.

http://dx.doi.org/10.1021/ja058066n

98.

Asymmetric Strecker Reaction of Aldimines Using Aqueous Potassium Cyanide by Phase-Transfer Catalysis of Chiral Quaternary Ammonium Salts with a Tetranaphthyl Backbone

Ooi, Takashi; Uematsu, Yukitaka; Maruoka, Keiji

J. Am. Chem. Soc. 2006, 128, 2548-2549.

http://dx.doi.org/10.1021/ja058066n

97.

N-Spiro Chiral Quaternary Ammonium Bromide Catalyzed Diastereo- and Enantioselective Conjugate Addition of Nitroalkanes to Cyclic α,β-Unsaturated Ketones under Phase-Transfer Conditions

Ooi, Takashi; Takada, Saki; Fujioka, Shingo; Maruoka, Keiji

Org. Lett. 2005, 7, 5143-5146.

http://dx.doi.org/10.1021/ol0517170

96.

Importance of Chiral Phase-Transfer Catalysts with Dual Functions in Obtaining High Enantioselectivity in the Michael Reaction of Malonates and Chalcone Derivatives

Ooi, Takashi; Ohara, Daisuke; Fukumoto, Kazuhiro; Maruoka, Keiji

Org. Lett. 2005, 7, 3195-3197.

http://dx.doi.org/10.1021/ol050902a

95.

Highly Enantioselective Phase-Transfer-Catalyzed Alkylation of Protected α-Amino Acid Amides toward Practical Asymmetric Synthesis of Vicinal Diamines, α-Amino Ketones, and α-Amino Alcohols

Ooi, Takashi; Takeuchi, Mifune; Kato, Daisuke; Uematsu, Yukitaka; Tayama, Eiji; Sakai, Daiki; Maruoka, Keiji

J. Am. Chem. Soc. 2005, 127, 5073-5083.

http://dx.doi.org/10.1021/ja0459328

94.

Dramatic Rate Enhancement of Asymmetric Phase-Transfer-Catalyzed Alkylations

Shirakawa, Seiji; Yamamoto, Kenichiro; Kitamura, Masanori; Ooi, Takashi; Maruoka, Keiji

Angew. Chem., Int. Ed. 2005, 44, 625-628.

http://dx.doi.org/10.1002/anie.200462035

93.

Asymmetric Synthesis of Functionalized Aza-Cyclic Amino Acids with Quaternary Stereocenters by a Phase-Transfer-Catalyzed Alkylation Strategy

Ooi, Takashi; Miki, Takashi; Maruoka, Keiji

Org. Lett. 2005, 7, 191-193.

http://dx.doi.org/10.1021/ol047921p

92.

Organoaluminum-Mediated Selective 1,2-Rearrangement of γ,γ-Disubstituted γ-Amino α,β-Unsaturated Carbonyl Compounds Leading to Unsymmetrically Substituted Pyrroles

Ooi, Takashi; Ohmatsu, Kohsuke; Ishii, Hiroki; Saito, Akira; Maruoka, Keiji

Tetrahedron Lett. 2004, 45, 9315-9317.

http://dx.doi.org/10.1016/j.tetlet.2004.10.126

91.

Meerwein-Ponndorf-Verley Alkynylation of Aldehydes: Essential Modification of Aluminum Alkoxides for Rate Acceleration and Asymmetric Synthesis

Ooi, Takashi; Miura, Tomoya; Ohmatsu, Kohsuke; Saito, Akira; Maruoka, Keiji

Org. Biomol. Chem. 2004, 2, 3312-3319.

http://dx.doi.org/10.1039/B411090K

90.

Anti-selective Asymmetric Synthesis of β-Hydroxy-α-Amino Acid Esters by the in Situ Generated Chiral Quaternary Ammonium Fluoride-Catalyzed Mukaiyama-Type Aldol Reaction

Ooi, Takashi; Taniguchi, Mika; Doda, Kanae; Maruoka, Keiji

Adv. Synth. Catal. 2004, 346, 1073-1076.

http://dx.doi.org/10.1002/adsc.200404111

89.

Highly Enantioselective Conjugate Addition of Nitroalkanes to Alkylidenemalonates Using Efficient Phase-Transfer Catalysis of N-Spiro Chiral Ammonium Bromides

Ooi, Takashi; Fujioka, Shingo; Maruoka, Keiji

J. Am. Chem. Soc. 2004, 126, 11790-11791.

http://dx.doi.org/10.1021/ja047047v

88.

Evaluation of the Relationship Between the Catalyst Structure and Regio- as well as Stereoselectivity in the Chiral Ammonium Bifluoride-Catalyzed Asymmetric Addition of Silyl Nitronates to α,β-Unsaturated Aldehydes

Ooi, Takashi; Morimoto, Kumiko; Doda, Kanae; Maruoka, Keiji

Chem. Lett. 2004, 33, 824-825.

http://dx.doi.org/10.1246/cl.2004.824

87.

Development of Highly Diastereo- and Enantioselective Direct Asymmetric Aldol Reaction of a Glycinate Schiff Base with Aldehydes Catalyzed by Chiral Quaternary Ammonium Salts

Ooi, Takashi; Kameda, Minoru; Taniguchi, Mika; Maruoka, Keiji

J. Am. Chem. Soc. 2004, 126, 9685-9694.

http://dx.doi.org/10.1021/ja048865q

86.

Catalytic Asymmetric Synthesis of a Nitrogen Analogue of Dialkyl Tartrate by Direct Mannich Reaction under Phase-Transfer Conditions

Ooi, Takashi; Kameda, Minoru; Fujii, Junichi; Maruoka, Keiji

Org. Lett. 2004, 6, 2397-2399.

http://dx.doi.org/10.1021/ol049215u

85.

Efficient Asymmetric Catalysis of Chiral Organoaluminum Complex for Enantioselective Ene Reactions of Aldehydes

Ooi, Takashi; Ohmatsu, Kohsuke; Uraguchi, Daisuke; Maruoka, Keiji

Tetrahedron Lett. 2004, 45, 4481-4484.

http://dx.doi.org/10.1016/j.tetlet.2004.04.052

84.

Design of New Chiral Phase-Transfer Catalysts with Dual Functions for Highly Enantioselective Epoxidation of α,β-Unsaturated Ketones

Ooi, Takashi; Ohara, Daisuke; Tamura, Masazumi; Maruoka, Keiji

J. Am. Chem. Soc. 2004, 126, 6844-6845.

http://dx.doi.org/10.1021/ja048600b

83.

Stereoselective Terminal Functionalization of Small Peptides for Catalytic Asymmetric Synthesis of Unnatural Peptides

Maruoka, Keiji; Tayama, Eiji; Ooi, Takashi

Proc. Natl. Acad. Sci. USA 2004, 101, 5824-5829.

http://dx.doi.org/10.1073/pnas.0307725101

82.

Highly Enantioselective Alkylation of Glycine Methyl and Ethyl Ester Derivatives under Phase-Transfer Conditions: its Synthetic Advantage

Ooi, Takashi; Uematsu, Yukitaka; Maruoka, Keiji

Tetrahedron Lett. 2004, 45, 1675-1678.

http://dx.doi.org/10.1016/j.tetlet.2003.12.102

81.

Elucidation and Synthetic Utility of the Double Electrophilic Activation Phenomenon

Ooi, Takashi; Takahashi, Makoto; Yamada, Masao; Tayama, Eiji; Omoto, Kiyoyuki; Maruoka, Keiji

J. Am. Chem. Soc. 2004, 126, 1150-1160.

http://dx.doi.org/10.1021/ja030552s

80.

Practical Asymmetric Synthesis of Vicinal Diamines Through the Catalytic Highly Enantioselective Alkylation of Glycine Amide Derivatives

Ooi, Takashi; Sakai, Daiki; Takeuchi, Mifune; Tayama, Eiji; Maruoka, Keiji

Angew. Chem., Int. Ed. 2003, 42, 5868-5870.

http://dx.doi.org/10.1002/anie.200352658

79.

A New N-Spiro C2-Symmetric Chiral Quaternary Ammonium Bromide Consisting of 4,6-Disubstituted Biphenyl Subunit as an Efficient Chiral Phase-Transfer Catalyst

Ooi, Takashi; Kubota, Yasushi; Maruoka, Keiji

Synlett. 2003, 1931-1933.

http://dx.doi.org/10.1055/s-2003-41478

78.

Highly Enantioselective Construction of Quaternary Stereocenters on β-Keto Esters by Phase-Transfer Catalytic Asymmetric Alkylation and Michael Reaction

Ooi, Takashi; Miki, Takashi; Taniguchi, Mika; Shiraishi, Misato; Takeuchi, Mifune; Maruoka, Keiji

Angew. Chem., Int.l Ed. 2003, 42, 3796-3798.

http://dx.doi.org/10.1002/anie.200351469

http://dx.doi.org/10.1002/anie.200390567

77.

Fluorotetraphenylbismuth: A New Reagent for Efficient Regioselective α-Phenylation of Carbonyl Compounds

Ooi, Takashi; Goto, Ryoji; Maruoka, Keiji

J. Am. Chem. Soc. 2003, 125, 10494-10495.

http://dx.doi.org/10.1002/anie.200351469

http://dx.doi.org/10.1002/anie.200390567

76.

A Scalable Synthesis of (R)-3,5-Dihydro-4H-dinaphth[2,1-c:1'2'-e]azepine

Ikunaka, Masaya; Maruoka, Keiji; Okuda, Yoshiaki; Ooi, Takashi

Org. Proc. Res. Dev. 2003, 7, 644-648.

http://dx.doi.org/10.1021/op034067t

75.

Highly Enantioselective Michael Addition of Silyl Nitronates to α,β-Unsaturated Aldehydes Catalyzed by Designer Chiral Ammonium Bifluorides: Efficient Access to Optically Active γ-Nitro Aldehydes and Their Enol Silyl Ethers

Ooi, Takashi; Doda, Kanae; Maruoka, Keiji

J. Am. Chem. Soc. 2003, 125, 9022-9023.

http://dx.doi.org/10.1021/ja0352810

74.

New, Improved Procedure for the Synthesis of Structurally Diverse N-Spiro C2-Symmetric Chiral Quaternary Ammonium Bromides

Ooi, Takashi; Uematsu, Yukitaka; Maruoka, Keiji

J. Org. Chem. 2003, 68, 4576-4578.

http://dx.doi.org/10.1021/jo030032f

73.

Design of N-Spiro C2-Symmetric Chiral Quaternary Ammonium Bromides as Novel Chiral Phase-Transfer Catalysts: Synthesis and Application to Practical Asymmetric Synthesis of α-Amino Acids

Ooi, Takashi; Kameda, Minoru; Maruoka, Keiji

J. Am. Chem. Soc. 2003, 125, 5139-5151.

http://dx.doi.org/10.1021/ja021244h

72.

Isopropoxyaluminum 1,1'-Biphenyl-2-oxy-2'-perfluorooctanesulfonamide as a Catalyst for Tishchenko Reaction

Ooi, Takashi; Ohmatsu, Kohsuke; Sasaki, Kouji; Miura, Tomoya; Maruoka, Keiji

Tetrahedron Lett. 2003, 44, 3191-3193.

http://dx.doi.org/10.1016/S0040-4039(03)00472-6

71.

Highly Stereoselective N-Terminal Functionalization of Small Peptides by Chiral Phase-Transfer Catalysis

Ooi, Takashi; Tayama, Eiji; Maruoka, Keiji

Angew. Chem., Int. Ed. 2003, 42, 579-582.

http://dx.doi.org/10.1002/anie.200390167

70.

Asymmetric Skeletal Rearrangement of Symmetrically α,α-Disubstituted α-Amino Aldehydes: A New Entry to Optically Active α-Hydroxy Ketones

Ooi, Takashi; Saito, Akira; Maruoka, Keiji

J. Am. Chem. Soc. 2003, 125, 3220-3221.

http://dx.doi.org/10.1021/ja0292851

69.

Designer Chiral Quaternary Ammonium Bifluorides as an Efficient Catalyst for Asymmetric Nitroaldol Reaction of Silyl Nitronates with Aromatic Aldehydes

Ooi, Takashi; Doda, Kanae; Maruoka, Keiji

J. Am. Chem. Soc. 2003, 125, 2054-2055.

http://dx.doi.org/10.1021/ja0292851

68.

Direct Asymmetric Aldol Reactions of Glycine Schiff Base with Aldehydes Catalyzed by Chiral Quaternary Ammonium Salts

Ooi, Takashi; Taniguchi, Mika; Kameda, Minoru; Maruoka, Keiji

Angew. Chem., Int. Ed. 2002, 41, 4542-4544.

Wiley InterScience :: Article :: HTML Full Text

67.

Activation of Ether Functionality of Allyl Vinyl Ethers by Chiral Bis(organoaluminum) Lewis Acids: Application to Asymmetric Claisen Rearrangement

Tayama, Eiji; Saito, Akira; Ooi, Takashi; Maruoka, Keiji

Tetrahedron. 2002, 58, 8307-8312.

http://dx.doi.org/10.1016/S0040-4020(02)00981-X

66.

Evaluation of The Efficiency of the Chiral Quaternary Ammonium Salt β-Np-NAS-Br in the Organic-Aqueous Phase-Transfer Alkylation of a Protected Glycine Derivative

Ooi, Takashi; Uematsu, Yukitaka; Maruoka, Keiji

Adv. Synth. Catal. 2002, 344, 288-291.

10.1002/1615-4169

65.

Practical Oppenauer (OPP) Oxidation of Alcohols with a Modified Aluminum Catalyst

Ooi, Takashi; Otsuka, Hidehito; Miura, Tomoya; Ichikawa, Hayato; Maruoka, Keiji

Org. Lett. 2002, 4, 2669-2672.

http://dx.doi.org/10.1021/ol020094c

64.

Asymmetric Induction in the Neber Rearrangement of Simple Ketoxime Sulfonates under Phase-Transfer Conditions: Experimental Evidence for the Participation of an Anionic Pathway

Ooi, Takashi; Takahashi, Makoto; Doda, Kanae; Maruoka, Keiji

J. Am. Chem. Soc. 2002, 124, 7640-7641.

http://dx.doi.org/10.1021/ja0118791

63.

Conformationally Flexible, Chiral Quaternary Ammonium Bromides for Asymmetric Phase-Transfer Catalysis

Ooi, Takashi; Uematsu, Yukitaka; Kameda, Minoru; Maruoka, Keiji

Angew. Chem., Int. Ed. 2002, 41, 1551-1554.

10.1002/1521-3773

62.

Catalytic Meerwein-Ponndorf-Verley (MPV) and Oppenauer (OPP) Reactions: Remarkable Acceleration of the Hydride Transfer by Powerful Bidentate Aluminum Alkoxides

Ooi, Takashi; Miura, Tomoya; Itagaki, Yoshifumi; Ichikawa, Hayato; Maruoka, Keiji

Synthesis. 2002, 279-291.

DOI: 10.1055/s-2002-19802

61.

Esterification of Carboxylic Acids Catalyzed by in Situ Generated Tetraalkylammonium Fluorides

Ooi, Takashi; Sugimoto, Hayato; Doda, Kanae; Maruoka, Keiji

Tetrahedron Lett. 2001, 42, 9245-9248.

doi:10.1016/S0040-4039(01)02035-4

60.

A Convergent, Homochiral Bis(amino alcohol) for Obtaining High Enantioselectivity in the Addition of Diethylzinc to Aldehydes

Ooi, Takashi; Saito, Akira; Maruoka, Keiji

Chem. Lett. 2001, 1108-1109.

doi:10.1246/cl.2001.1108

59.

Practical Approach to the Meerwein-Ponndorf-Verley Reduction of Carbonyl Substrates with New Aluminum Catalysts

Ooi, Takashi; Ichikawa, Hayato; Maruoka, Keiji

Angew. Chem., Int. Ed. 2001, 40,3610-3612.

10.1002/1521-3773

58.

Concise, Catalytic Asymmetric Synthesis of Tetrahydroisoquinoline- and Dihydroisoquinoline-3-carboxylic Acid Derivatives

Ooi, Takashi; Takeuchi, Mifune; Maruoka, Keiji

Synthesis. 2001, 1716-1718.

DOI: 10.1055/s-2001-16747

57.

Advantage of Anaerobic Conditions in the Highly Enantioselective Synthesis of α,α-Dialkyl-α-amino Acids by Chiral Phase-Transfer Catalysis

Ooi, Takashi; Takeuchi, Mifune; Ohara, Daisuke; Maruoka, Keiji

Synlett. 2001, 1185-1187.

DOI: 10.1055/s-2001-15167

56.

o-(o-Iodophenyl)phenylselenenyl Ethers/t-BuLi System as an Alkyllithium Equivalent with Structural Variations

Ooi, Takashi; Sakai, Daiki; Takada, Mio; Komatsu, Naoki; Maruoka, Keiji

Synlett. 2001, 791-792.

DOI: 10.1055/s-2001-14622

55.

Utilization of o-[(Z)-2-Trimethylsilyl-2-iodovinyl]phenylthio Derivatives as Carbon Radical Precursors by Anchimeric Approach

Ooi, Takashi; Furuya, Mayumi; Sakai, Daiki; Hokke, Yasutoshi; Maruoka, Keiji

Synlett. 2001, 541-543.

DOI: 10.1055/s-2001-12338

54.

Distinct Advantage of the in Situ Generation of Quaternary Ammonium Fluorides under Phase-Transfer Conditions toward Catalytic Asymmetric Synthesis

Ooi, Takashi; Doda, Kanae; Maruoka, Keiji

Org. Lett. 2001, 3, 1273-1276.

DOI: 10.1021/ol000382d

53.

Rapid and Mild Generation of Carbon Radicals from o-(o-Iodophenyl)phenylthio Derivatives by an Anchimeric Approach

Ooi, Takashi; Furuya, Mayumi; Sakai, Daiki; Maruoka, Keiji

Adv. Synt. Catal. 2001, 343, 166-168.

10.1002/1615-4169

52.

Facile Conversion of Trialkylsilyl Esters to Alkyl Esters Mediated by Tetrabutylammonium Fluoride Trihydrate

Ooi, Takashi; Sugimoto, Hayato; Maruoka, Keiji

Heterocycles. 2001, 54, 593-596.

DOI:

51.

Remarkable Template Effect of a Lewis Acid Receptor in Intramolecular Radical Cyclization: Control of Reaction Pathway as well as Stereochemistry

Ooi, Takashi; Hokke, Yasutoshi; Tayama, Eiji; Maruoka, Keiji

Tetrahedron. 2001, 57, 135-144.

doi:10.1016/S0040-4020(00)01007-3

50.

Zr(OBut)4 as an Effective Promoter for the Meerwein-Ponndorf-Verley Alkynylation and Cyanation of Aldehydes: Development of a New Asymmetric Cyanohydrin Synthesis

Ooi, Takashi; Miura, Tomoya; Takaya, Keisuke; Ichikawa, Hayato; Maruoka, Keiji

Tetrahedron. 2001, 57, 867-873.

doi:10.1016/S0040-4020(00)01040-1

49.

Facile Synthesis of L-Dopa tert-Butyl Ester by Catalytic Enantioselective Phase-Transfer Alkylation

Ooi, Takashi; Kameda, Minoru; Tannai, Hidenori; Maruoka, Keiji

Tetrahedron Lett. 2000, 41, 8339-8342.

doi:10.1016/S0040-4039(00)01443-X

48.

Dramatic Rate Enhancement by Ultrasonic Irradiation in Liquid-Liquid Phase-Transfer Catalytic Reactions

Ooi, Takashi; Tayama, Eiji; Doda, Kanae; Takeuchi, Mifune; Maruoka, Keiji

Synlett. 2000, 41, 1500-1502.

DOI: 10.1055/s-2000-7652

47.

Chiral Zirconium Alkoxides-Mediated Asymmetric Meerwein-Ponndorf-Verley Cyanation of Aldehydes

Ooi, Takashi; Takaya, Keisuke; Miura, Tomoya; Ichikawa, Hayato; Maruoka, Keiji

Synlett. 2000, 41, 1133-1134.

DOI: 10.1055/s-2000-6761

46.

Unique Synthetic Utility of BF3・OEt2 in the Highly Diastereoselective Reduction of Hydroxy Carbonyl and Dicarbonyl Substrates

Ooi, Takashi; Uraguchi, Daisuke; Morikawa, Junko; Maruoka, Keiji

Org. Lett. 2000, 2, 2015-2017.

DOI: 10.1055/s-2000-6761

45.

Practical Catalytic Enantioselective Synthesis of α,α-Dialkyl-α-amino Acids by Chiral Phase-Transfer Catalysis

Ooi, Takashi; Takeuchi, Mifune; Kameda, Minoru; Maruoka, Keiji

J. Am. Chem. Soc. 2000, 122, 5228-5229.

DOI: 10.1021/ja0007051

44.

Efficient Catalytic Procedure for Etherification of Alcohols with MeAl(NTf2)2

Ooi, Takashi; Ichikawa, Hayato; Itagaki, Yoshifumi; Maruoka, Keiji

Heterocycles. 2000, 52, 575-578.

DOI:

43.

Zr(OtBu)4 as a New Promoter for the Meerwein-Ponndorf-Verley Alkynylation and Cyanation of Aldehydes

Ooi, Takashi; Takaya, Keisuke; Miura, Tomoya; Maruoka, Keiji

Synlett. 2000, 69-70.

DOI: 10.1055/s-2000-6476

42.

"Amphiphilic" Cleavage of γ-Stannyl Ketones with ATPH/RLi: Application to Enone Fragmentation by the Conjugate Addition-Cleavage Sequence

Kondo, Yuichiro; Kon-i, Kana; Iwasaki, Atsuko; Ooi, Takashi; Maruoka, Keiji

Angew. Chem., Int. Ed. 2000, 39, 414-416.

DOI:

41.

Highly Efficient Amphiphilic Cleavage of γ-Iodo Carbonyl Substrates with Aluminum Tris(2,6-diphenylphenoxide)/t-BuLi System

Kondo, Yuichiro; Kon-I, Kana; Ooi, Takashi; Maruoka, Keiji

Tetrahedron Lett. 1999, 40, 9041-9044.

doi:10.1016/S0040-4039(99)01718-9

40.

Catalytic, High-Speed Tishchenko Reaction Using (2,7-Dimethyl-1,8-biphenylenedioxy)bis(diisopropoxyaluminum) as a Powerful Bidentate Catalyst

Ooi, Takashi; Miura, Tomoya; Takaya, Keisuke; Maruoka, Keiji

Tetrahedron Lett. 1999, 40, 7695-7698.

doi:10.1016/S0040-4039(99)01555-5

39.

Remarkable Catalytic Activity of Me3Ga in the Alkylation of Hetero-Substituted Epoxides with Alkynyllithiums

Ooi, Takashi; Morikawa, Junko; Ichikawa, Hayato; Maruoka, Keiji

Tetrahedron Lett. 1999, 40, 5881-5884.

doi:10.1016/S0040-4039(99)01096-5

38.

Molecular Design of a C2-Symmetric Chiral Phase-Transfer Catalyst for Practical Asymmetric Synthesis of α-Amino Acids

Ooi, Takashi; Kameda, Minoru; Maruoka, Keiji

J. Am. Chem. Soc. 1999, 121, 6519-6520.

DOI: 10.1021/ja991062w

37.

Efficient Synthesis of Aromatic sec-Amides from Esters. Synthetic Utility of Dilithium Amides

Ooi, Takashi; Tayama, Eiji; Yamada, Masao; Maruoka, Keiji

Synlett. 1999, 729-730.

DOI: 10.1055/s-1999-2731

36.

Hypercoordination of Aluminum: Evidence for the Implication of Pentacoordinate Complexes in the R2AlCl-Promoted Reduction of Alkoxycarbonyl Substrates

Ooi, Takashi; Morikawa, Junko; Uraguchi, Daisuke; Maruoka, Keiji

Tetrahedron Lett. 1999, 40, 2993-2996.

doi:10.1016/S0040-4039(99)00401-3

35.

Pentacoordinate Organoaluminum Chemistry: Catalytic Efficiency of Me3Al in the Epoxide Cleavage with Alkynyllithiums

Ooi, Takashi; Kagoshima, Naoko; Ichikawa, Hayato; Maruoka, Keiji

J. Am. Chem. Soc. 1999, 121, 3328-3333.

DOI: 10.1021/ja9842464

34.

Simultaneous Functional Group Manipulation in the Meerwein-Ponndorf-Verley Reduction Process Catalyzed by Bidentate Aluminum Reagent

Ooi, Takashi; Itagaki, Yoshifumi; Miura, Tomoya; Maruoka, Keiji

Tetrahedron Lett. 1999, 40, 2137-2138.

doi:10.1016/S0040-4039(99)00131-8

33.

Unique Property of Copper(I) Chloride as a Radical Initiator as well as a Lewis Acid: Application to CuCl-Catalyzed Aldol Reaction of α,β-Unsaturated Ketones with Bu3SnH

Ooi, Takashi; Doda, Kanae; Sakai, Daiki; Maruoka, Keiji

Tetrahedron Lett. 1999, 40, 2133-2136.

doi:10.1016/S0040-4039(99)00130-6

32.

Unprecedented Encapsulation of Carbonyl Guest with Designer Lewis Acid Receptor

Ooi, Takashi; Kondo, Yuichiro; Maruoka, Keiji

Angew. Chem., Int. Ed. 1998, 37, 3039-3041.

DOI:

31.

Pentacoordinate vs. Tetracoordinate Complexation for Alkoxycarbonyl Compounds with Dialkylboron Triflates and Trifluoroacetates

Ooi, Takashi; Uraguchi, Daisuke; Maruoka, Keiji

Tetrahedron Lett. 1998, 39, 8105-8108.

doi:10.1016/S0040-4039(98)01798-5

30.

Highly Efficient, Catalytic Meerwein-Ponndorf-Verley Reduction with a Novel Bidentate Aluminum Catalyst

Ooi, Takashi; Miura, Tomoya; Maruoka, Keiji

Angew. Chem., Int. Ed. 1998, 37, 2347-2349.

DOI:

29.

First Meerwein-Ponndorf-Verley Alkynylation: Nonorganometallic Way for Carbonyl Alkylations

Ooi, Takashi; Miura, Tomoya; Maruoka, Keiji

J. Am. Chem. Soc. 1998, 120, 10790-10791.

DOI: 10.1021/ja9821347

28.

Organoaluminum-Promoted Selective Addition to Fluorinated Carbonyl Compounds via Pentacoordinate Trialkylaluminum Complexes

Ooi, Takashi; Kagoshima, Naoko; Uraguchi, Daisuke; Maruoka, Keiji

Tetrahedron Lett. 1998, 39, 7105-7108.

doi:10.1016/S0040-4039(98)01508-1

27.

Facile and Selective Alkylation of 3,3,3-Trifluoropropene Oxide with Organoaluminum Reagents via Pentacoordinate Trialkylaluminum Complexes

Ooi, Takashi; Furuya, Mayumi; Maruoka, Keiji

Chem. Lett. 1998, 817-818.

doi:10.1246/cl.1998.817

26.

Dilithium 2,2'-Methylenebis(4,6-di-tert-butylphenoxide) as a Bidentate Lewis Acid in Organic Synthesis

Ooi, Takashi; Saito, Akira; Maruoka, Keiji

Tetrahedron Lett. 1998, 39, 3745-3748.

doi:10.1016/S0040-4039(98)00575-9

25.

Selective Conjugate Alkylation by Alkyllithium Nucleophiles of α,β,γ,δ-Unsaturated Aldehydes with Functionalized Lewis Acid Receptors

Ooi, Takashi; Kondo, Yuichiro; Kon-i, Kana; Maruoka, Keiji

Chem. Lett. 1998, 403-404.

doi:10.1246/cl.1998.403

24.

SHypercoordination of Boron and Aluminum: Synthetic Utility as Chelating Lewis Acids

Ooi, Takashi; Uraguchi, Daisuke; Kagoshima, Naoko; Maruoka, Keiji

J. Am. Chem. Soc. 1998, 120, 5327-5328.

DOI: 10.1021/ja9736828

23.

Rate acceleration in Nucleophilic Alkylation of Carbonyl Compounds with a New Template Containing Two Metallic Centers

Ooi, Takashi; Takahashi, Makoto; Maruoka, Keiji

Angew. Chem., Int. Ed. 1998, 37, 835-837.

DOI:

22.

Organoaluminum-Promoted Rearrangement of Epoxysilanes to α-Silylaldehydes

Ooi, Takashi; Kiba, Toshitaka; Maruoka, Keiji

Chem. Lett. 1997, 519-520.

doi:10.1246/cl.1997.519

21.

Bidentate Organoaluminum Lewis Acid for Selective Activation of Carbonyl Over Acetal Functionality: Chemoselective Functionalization

Ooi, Takashi; Tayama, Eiji; Takahashi, Makoto; Maruoka, Keiji

Tetrahedron Lett. 1997, 38, 7403-7406.

doi:10.1016/S0040-4039(97)01735-8

20.

Organoaluminum-Catalyzed Alkylation by tert-Alkyl Fluorides: Synthetic utility of the Al-F interaction

Ooi, Takashi; Uraguchi, Daisuke; Kagoshima, Naoko; Maruoka, Keiji

Tetrahedron Lett. 1997, 38, 5679-5682.

doi:10.1016/S0040-4039(97)01237-9

19.

Conjugate Allylation to α,β-Unsaturated Aldehydes with the New Chemzyme p-F-ATPH

Ooi, Takashi; Kondo, Yuichiro; Maruoka, Keiji

Angew. Chem., Int. Ed. Engl. 1997, 36, 1183-1185.

DOI:

18.

Remarkable Template Effect of a Lewis Acidic Receptor in Intramolecular Radical Cyclizations

Ooi, Takashi; Hokke, Yasutoshi; Maruoka, Keiji

Angew. Chem., Int. Ed. Engl. 1997, 36, 1181-1183.

DOI:

17.

Evaluation of Several Fluorinated ATPH Derivatives as Functionalized Lewis Acid Receptors for Conjugate Alkylation to α,β-Unsaturated Aldehydes with Alkyllithium Nucleophiles

Ooi, Takashi; Kondo, Yuichiro; Miura, Tomoya; Maruoka, Keiji

Tetrahedron Lett. 1997, 38, 3951-3954.

doi:10.1016/S0040-4039(97)00787-9

16.

Conjugate Allylation to α,β-Unsaturated Aldehydes with Amphiphilic Alkylation System, ATPH/Allylcerium Reagents

Ooi, Takashi; Miura, Tomoya; Kondo, Yuichiro; Maruoka, Keiji

Tetrahedron Lett. 1997, 38, 3947-3950.

doi:10.1016/S0040-4039(97)00786-7

15.

Fluorine-Assisted Selective Alkylation to Fluorinated Epoxides and Carbonyl Compounds: Implication of Pentacoordinate Trialkylaluminum Complexes

Ooi, Takashi; Kagoshima, Naoko; Maruoka, Keiji

J. Am. Chem. Soc. 1997, 119, 5754-5755.

DOI: 10.1021/ja964113n

14.

Organoaluminum-Promoted Cyclization of Olefinic Epoxides. A New and Stereoselective Approach to Cyclohexane Frameworks

Murase, Noriaki; Maruoka, Keiji; Ooi, Takashi; Yamamoto, Hisashi

Bull. Chem. Soc. Jpn. 1997, 70, 707-711.

doi:10.1246/bcsj.70.707

13.

(2,7-Dimethyl-1,8-biphenylenedioxy)bis(dimethylaluminum) as a Bidentate Lewis Acid: Its Reactivity and Selectivity in Organic Synthesis

Ooi, Takashi; Takahashi, Makoto; Maruoka, Keiji

J. Am. Chem. Soc. 1996, 118, 11307-11308.

doi:10.1246/bcsj.70.707

12.

Asymmetric Diels-Alder Reaction of Unsymmetrical Maleates. A Chemical Access to Chiral, Unsymmetrical cis-Cyclohexene-1,2-dicarboxylates

Maruoka, Keiji; Akakura, Matsujiro; Saito, Susumu; Ooi, Takashi; Yamamoto, Hisashi

J. Am. Chem. Soc. 1994, 116, 6153-8.

DOI: 10.1021/ja00093a013

11.

Unprecedented Stereochemical Control in the Intramolecular Ene-Reactions of δ,ε-Unsaturated Aldehydes Using Exceptionally Bulky Organoaluminum Reagents: Elucidation of the Transition State

Ooi, Takashi; Maruoka, Keiji; Yamamoto, Hisashi

Tetrahedron. 1994, 50, 6505-22.

doi:10.1016/S0040-4020(01)89682-4

10.

Lewis Acid-Promoted Selective Rearrangement of Trisubstituted Epoxides to Aldehydes or Ketones

Maruoka, Keiji; Murase, Noriaki; Bureau, Ronan; Ooi, Takashi; Yamamoto, Hisashi

Tetrahedron. 1994, 50, 3663-72.

doi:10.1016/S0040-4020(01)90389-8

9.

Migratory Aptitude of Alkyl Substituents in the MABR-Promoted Epoxide Rearrangement [MABR = Methylaluminum Bis(4-bromo-2,6-di-tert-butylphenoxide)]

Maruoka, Keiji; Ooi, Takashi; Yamamoto, Hisashi

Tetrahedron. 1992, 48, 3303-12.

doi:10.1016/0040-4020(92)85006-Z

8.

A New Cyclization of Olefinic Epoxides by Modified Organoaluminum Reagents via Epoxide Rearrangement and Subsequent Intramolecular Ene Reaction

Maruoka, Keiji; Murase, Noriaki; Ooi, Takashi; Yamamoto, Hisashi

Synlett. 1991, 857-8.

DOI: 10.1055/s-1991-20901

7.

Organoaluminum-Catalyzed Rearrangement of Epoxides. A Facile Route to the Synthesis of Optically Active β-Siloxy Aldehydes

Maruoka, Keiji; Ooi, Takashi; Nagahara, Shigeru; Yamamoto, Hisashi

Tetrahedron. 1991, 47, 6983-98.

doi:10.1016/S0040-4020(01)96153-8

6.

A New Stereoselective Approach to Oxygenated Carbocycles: Asymmetric Synthesis of the Cyclohexyl Fragment of FK-506

Maruoka, Keiji; Saito, Susumu; Ooi, Takashi; Yamamoto, Hisashi

Synlett. 1991, 579-80.

DOI: 10.1055/s-1991-21983

5.

Selective Rearrangement of Trisubstituted Epoxides to Aldehydes or Ketones

Maruoka, Keiji; Bureau, Ronan; Ooi, Takashi; Yamamoto, Hisashi

Synlett. 1991, 491-2.

DOI: 10.1055/s-1991-20773

4.

Selective Reduction of Methylenecycloalkane Oxides with 4-Substituted Diisobutylaluminum 2,6-Di-tert-butylphenoxides

Maruoka, Keiji; Saito, Susumu; Ooi, Takashi; Yamamoto, Hisashi

Synlett. 1991, 255-6.

DOI: 10.1055/s-1991-20698

3.

Unprecedented Stereochemical Control in the Organoaluminum-Promoted Intramolecular Ene Reactions of δ,ε-Unsaturated Aldehydes

Maruoka, Keiji; Ooi, Takashi; Yamamoto, Hisashi

J. Am. Chem. Soc. 1990, 112, 9011-12.

DOI: 10.1021/ja00180a073

2.

An Efficient, Catalytic Procedure for Epoxide Rearrangement

Maruoka, Keiji; Nagahara, Shigeru; Ooi, Takashi; Yamamoto, Hisashi

Tetrahedron Lett. 1989, 30, 5607-10.

doi:10.1016/S0040-4039(01)93811-0

1.

Organoaluminum-Promoted Rearrangement of Epoxy Silyl Ethers to β-Siloxy Aldehydes

Maruoka, Keiji; Ooi, Takashi; Yamamoto, Hisashi

J. Am. Chem. Soc. 1989, 111, 6431-2.

DOI: 10.1021/ja00198a070

ページの先頭へ

総説等 : Reviews

18.

Chemistry of Ammonium Betaines: Application to Ion-Pair Catalysis for Selective Organic Transformations

Uraguchi, Daisuke; Ooi, Takashi

J. Synth. Org. Chem. Jpn. 2018, 76, 1144-1153.

https://doi.org/10.5059/yukigoseikyokaishi.76.1144

17.

Design of supramolecular chiral ligands for asymmetric metal catalysis

Kohsuke Ohmatsu, Takashi Ooi

Tetrahedron Letters 2015, 56, 2043-2048.

http://dx.doi.org/10.1016/j.tetlet.2015.02.096

16.

Development of Ion-Paired Chiral Ligands for Asymmetric Transition-Metal Catalysis

Kohsuke Ohmatsu, Takashi Ooi

J. Synth. Org. Chem. Jpn. 2015, 73, 140-150.

http://doi.org/10.5059/yukigoseikyokaishi.73.140

15.

Development of P-Spiro Chiral Aminophosphonium Salts as a New Class of Versatile Organic Molecular Catalyst

Uraguchi, Daisuke; Ooi, Takashi

J. Synth. Org. Chem. Jpn. 2010, 68, 1185-1194.

http://www.jstage.jst.go.jp/article/yukigoseikyokaishi/68/11/1185/_pdf/-char/ja/

14.

Development of Ion-Pair Cooperative Asymmetric Catalyses of Chiral Phosphonium Salts Possessing an Organic Anion

Ueki, Yusuke; Uraguchi, Daisuke; Ooi, Takashi

Shokubai 2010, 52, 509-514.

http://www.shokubai.org/jnl/tmpPdf/1295275473a.pdf

13.

Development of D2-Symmetric Chiral Tetraaminophosphonium Salts as a Catalyst for Asymmetric Phase-Transfer Reactions

Uraguchi, Daisuke; Ooi, Takashi

Finechemicals 2010, 39, 42-48.

12.

Development and Applications of C2-Symmetric, Chiral, Phase-Transfer Catalysts

Ooi, Takashi; Maruoka, Keiji

Aldrichimia Acta 2007, 40, 77-86.

http://www.sigmaaldrich.com/etc/medialib/docs/Aldrich/Acta/al_acta_40_03.Par.0001.File.tmp/al_acta_40_03.pdf

11.

Design of Chiral Organocatalysts for Practical Asymmetric Synthesis of Amino Acid Derivatives

Maruoka, Keiji; Ooi, Takashi; Kano, Taichi

Chem. Commun 2007, 1487-1495.

DOI: 10.1039/b613049f

10.

Recent Advances in Asymmetric Phase-Transfer Catalysis

Ooi, Takashi; Maruoka, Keiji

Angew. Chem., Int. Ed 2007, 46, 4222-4266.

10.1002/anie.200601737

9.

Asymmetric Organocatalysis of Structurally Well-Defined Chiral Quaternary Ammonium Fluorides

Ooi, Takashi; Maruoka, Keiji

Acc. Chem. Res 2004, 37, 526-533.

DOI: 10.1021/ar030060k

8.

Enantioselective Amino Acid Synthesis by Chiral Phase-Transfer Catalysis

Maruoka, Keiji; Ooi, Takashi

Chem. Rev 2003, 103, 3013-3028.

DOI: 10.1021/cr020020e

7.

Enantioselective synthesis of α-amino acids by chiral phase-transfer catalysis

Ooi, Takashi; Maruoka, Keiji

Yuki Gosei Kagaku Kyokaishi 2003, 61, 1195-1206.

journal@chive

6.

Chemistry of chelate-type hypervalent boron and aluminum. Utilization for selective organic synthesis

Uraguchi, Daisuke; Ooi, Takashi; Maruoka, Keiji

Yuki Gosei Kagaku Kyokaishi 2000, 58, 14-22.

journal@chive

5.

The Synthetic Utility of the Hypercoordination of Boron and Aluminum

Maruoka, Keiji; Ooi, Takashi

Chem. Eur. J. 1999, 5, 829-833.

DOI:

4.

Exceptionally Bulky Lewis Acidic Reagent, MAD

Ooi, Takashi; Maruoka, Keiji

Rev. Heteroatom Chem. 1998, 18, 61-85.

3.

High activation of carbonyl groups with bidentate Lewis acid catalysts

Ooi, Takashi; Asao, Naoki; Maruoka, Keiji

Yuki Gosei Kagaku Kyokaishi 1998, 56, 377-385.

journal@chive

2.

Exceptionally bulky Lewis acidic reagent, MAD

Ooi, Takashi; Maruoka, Keiji

Yuki Gosei Kagaku Kyokaishi 1996, 54, 200-11.

journal@chive

1.

Rearrangement of trans-stilbene oxide to diphenylacetaldehyde with catalytic methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (oxirane, 2,3-diphenyl-, trans- to benzeneacetaldehyde, α-phenyl-)

Ooi, Takashi; Maruoka, Keiji; Yamamoto

Hisashi Organic Syntheses 1995, 72, 95-103.

http://www.orgsyn.org/orgsyn/pdfs/CV9P0356.pdf

ページの先頭へ

解説・紀要等 :

18.

「有機イオン対の触媒化学:構造に由来する機能発現」

浦口 大輔, 大松 亨介, 大井 貴史

ケミカルタイムズ 2018, (2), 19-25.

https://www.kanto.co.jp/dcms_media/other/CT_248_all.pdf

17.

「有機分子触媒の化学−「輪」をもって尊しとなす−」

浦口 大輔, 大井 貴史

現代化学 2017, 558(9), 52-56.

16.

α-アミノカルボニル化合物の効率的不斉合成

中島 翼,大松 亨介, 大井 貴史

PHARMSTAGE 2017, 17, 61-67.

15.

「[5.5]-P-スピロ型キラルテトラアミノホスホニウム塩を用いる触媒的分子変換」

浦口 大輔, 大井 貴史

Wako Organic Square 2017, 59(3), 2-5.

http://www.wako-chem.co.jp/siyaku/journal/org/pdf/org59.pdf

14.

Virtual Issue Posts on Organocatalysis: Design, Applications, and Diversity

Ooi, Takashi

ACS Catal. 2015, 5, 6980-6988.

http://pubs.acs.org/doi/10.1021/acscatal.5b02354

13.

「忘れられた反応剤Davis’オキサジリジン」

浦口 大輔, 堤 亮祐, 大井 貴史

月刊「化学」 2013, 68, 66-67.

12.

「D2対称型光学活性テトラアミノホスホニウム塩の創製と相間移動触媒反応への応用」

浦口 大輔, 大井 貴史

月刊ファインケミカル 2010, 39, 42-48.

11.

Heat and Light Switch a Chiral Catalyst and Its Products

Ooi, Takashi

Science 2011, 331, 1395-1396.

http://www.sciencemag.org/content/331/6023/1395.full?rss=1

10.

「光学活性な炭素の三角形を作る―Corey-Chaykovsky反応と親電子剤活性化法の組み合わせ」

浦口 大輔, 大井 貴史

化学 2008, 63, 66-67.

9.

「二相系でのイミンの系内発生を活かした触媒的不斉合成」

大井 貴史

Organometallic News 2007, 40-43.

8.

「光学活性ジエン配位子が与える新しい不斉環境」

大井 貴史

Organometallic News 2004, 134.

7.

「不斉有機触媒としてのキラル相間移動触媒-アミノ酸合成を中心として」

大井 貴史, 丸岡 啓二

化学と工業 2004, 57, 711-715.

6.

「光学活性相間移動触媒が拓く有機合成−二相系での実用的不斉合成プロセス」

亀田 稔, 大井 貴史, 丸岡 啓二

化学 2000, 55, 70-71.

5.

「ルイス酸・塩基を分子内にもつアルミニウム触媒−高度に制御された反応場をもつ不斉触媒の開発」

市川 隼人, 大井 貴史

化学 1999, 54, 65-66.

4.

Synthesis of anticancer taxol using Lewis acid-type artificial enzyme

Maruoka, Keiji; Asao, Naoki; Ooi, Takashi

Ikagaku Oyo Kenkyu Zaidan Kenkyu Hokoku 1998, 16, 228-230.

3.

「ルイス酸のデザイン-二点配位型システムの構築-」

大井 貴史

化学と工業 1997, 50, 1496-1499.

2.

「自己複製する人工分子」

大井 貴史

ファルマシア 1995, 31, 1034-1035.

1.

「エポキシドの選択的転位を機軸とする不斉アルドール合成」

大井 貴史, 丸岡 啓二, 山本 尚

化学 1993, 48, 218-219.

ページの先頭へ

著書等 : Books

27.

“Organic Molecular Catalysts in Radical Chemistry: Challenges Toward Selective Transformations”

Daisuke Uraguchi, Kohsuke Ohmatsu, Takashi Ooi
Molecular Technology: Synthesis Innovation, Volume 4” H. Yamamoto and T. Kato Eds. Wiley-VCH; 163-197 (2019)

26.

「多機能型キラルオニウム塩の設計に基づく高選択的分子変換」

大松 亨介, 浦口 大輔, 大井 貴史
有機分子触媒の開発と工業利用” シーエムシー出版; xxx-xxx (2018)

25.

「イオン対を中心とした不斉塩基触媒」

浦口 大輔, 大井 貴史
CSJカレントレビュー「有機分子触媒の化学」” 日本化学会; 109-117 (2016)

24.

“Site-Selective Conjugate Addition through Catalytic Generation of Ion-Pairing Intermediates”

Daisuke Uraguchi, Takashi Ooi
Topics in Current Chemistry: Site Selective Catalysis” T. Kawabata Ed. Springer; 55-84 (2016)

23.

「イオン性キラル触媒〜新しい分子設計へのこだわり〜」

大松 亨介, 大井 貴史
CSJカレントレビュー「キラル化学:その起源から最新のキラル材料研究まで」” 八島 栄治 日本化学会; (2013)

22.

"Axially Chiral C2-Symmetric Catalysts"

Uraguchi, Daisuke; Kohsuke, Ohmatsu; Ooi, Takashi

"Comprehensive Enantioselective Organocatalysis" Wiley-VCH Verlag GmbH; 161-193 (2013)

21.

"Asymmetric Phase-Transfer Catalysis"

Kohsuke, Ohmatsu; Uraguchi, Daisuke; Ooi, Takashi

"Stereoselective Synthesis of Drugs and Natural Products" Wiley; 119-144 (2013)

20.

"Recent Topics in Cooperative Catalysis: Comment 2"

Ooi, Takashi

"Organic Chemistry-Breakthroughs and Perspectives" Wiley; 402405 (2012)

19.

"1,4,6,9-Tetraaza-5λ5-phosphaspiro[4.4]non-5-ene, 3,8-bis(1-methylethyl)-2,2,7,7-tetrakis(4-methylphenyl)-, hydrochloride (1:1), (3R,5R,8R)-"

Uraguchi, Daisuke; Ooi, Takashi

"ELECTRONIC ENCYCLOPEDIA OF REAGENTS FOR ORGANIC SYNTHESIS (e-EROS)" Wiley; RN01546 (2012)

18.

"6.1 C-C Bond Formation: Alkylation"

Uraguchi, Daisuke; Ooi, Takashi

"COMPREHENSIVE CHIRALITY" Elsevier Science; 1-36 (2012)

17.

"Hydrogen-Bonding Catalysts Other than Ureas and Thioureas"

Uraguchi, Daisuke; Ooi, Takashi

"Science of Synthesis: Asymmetric Organicatalysis 2" Thieme; 413-435 (2012)

16.

"Development of phase-transfer-catalyzed asymmetric Strecker reaction based on the molecular design of chiral quaternary ammonium salts"

Ooi, Takashi

"ACS Symposium Series (2009), 1009(Asymmetric Synthesis and Application of .alpha.-Amino Acids)" ACS Publications; 177-189 (2009)

15.

"Chiral quaternary ammonium fluorides for asymmetric synthesis"

Shirakawa, Seiji; Ooi, Takashi; Maruoka, Keiji

"Asymmetric Phase Transfer Catalysis" K. Maruoka Eds. Wiley-VCH; 189-206 (2008)

14.

"Cinchona-derived chiral phase-transfer catalysts for amino acid synthesis"

T. Ooi

"Asymmetric Phase Transfer Catalysis" K. Maruoka Eds. Wiley-VCH; 9-33 (2008)

13.

"Chiral Carbonyl Lewis Acid Complexes in Asymmetric Syntheses"

K. Maruoka, T. Ooi

"Asymmetric Synthesis - The Essentials" M. Christmann, S. Bra¨se Eds. VCH; 121-125 (2007)

12.

"Ammonium Ions as Chiral Templates"

T. Ooi, K. Maruoka

"Enantioselective Organocatalysis: Reactions and Experimental Procedures" P. I. Dalko Ed. Wiley; 121-150 (2007)

11.

"Phase-Transfer Catalysis"

T. Ooi, K. Maruoka

"Quaternary Stereocenters" J. Christoffers and A. Baro Eds. Wiley-VCH; 265-285 (2005)

10.

"Aluminum Alkoxides, Phenoxides, Thiolates, Selenolates and Amides"

T. Ooi, K. Maruoka

"Science of Synthesis Houben-Weyl Method of Molecular Transformations, Compounds of Groups 13 and 2" H. Yamamoto Ed. Springer; 7, 131-246 (2004)

9.

「有機アルミニウム化合物を用いる合成反応」

大井 貴史, 丸岡 啓二

「実験化学講座 第5版 有機化合物の合成Y」 村上正浩編,丸善株式会社,119-148 (2004)

8.

「官能基変換反応 (オレフィン類の異性化反応、エポキシド類の開環反応、エステル類やアミド類の加水分解反応及び加アルコール分解反応)」

大井 貴史, 丸岡 啓二

「化学便覧 基礎編 第6版」 日本化学会編,丸善株式会社,12.10.4a-12.10.4c (2004)

7.

「光学活性相間移動触媒を用いるグリシンの不斉アルキル化」

大井 貴史, 丸岡 啓二

「有機合成のための触媒反応103」 檜山爲次郎・野崎京子編,東京化学同人,146-147 (2004)

6.

「アルミニウム(Al)」

丸岡 啓二, 大井 貴史

「有機金属反応剤ハンドブック」 玉尾皓平編著,化学同人,49-55 (2003)

5.

"Design of Artificial Acid and Base Catalysts for Selective Organic Synthesis"

K. Maruoka, T. Ooi

"My Favorite Organic Synthesis" The Society of Synthetic Organic Chemistry, Japan Ed. Kagaku-Dojin Publishing Co., Inc.; 98-99 (2002)

4.

"Achiral Al(III) Lewis Acids"

T. Ooi, K. Maruoka

"Lewis Acids in Organic Synthesis" H. Yamamoto Ed. Wiley-VCH; 191-281 (2000)

3.

"Carbonyl-Lewis Acid Complexes"

T. Ooi, K. Maruoka

"Modern Carbonyl Chemistry" J. Otera Ed. Wiley-VCH; 1-32 (2000)

2.

"Hetero-Diels-Alder and Related Reactions"

T. Ooi, K. Maruoka

"Comprehensive Asymmetric Catalysis" E. N. Jacobsen, A. Pfaltz and H. Yamamoto Eds. Springer; 1237-1254 (1999)

1.

「有機化学 基礎の基礎 コンセプト 10-19」

大井 貴史, 丸岡 啓二

「有機化学 基礎の基礎 100のコンセプト」 山本嘉則編著,化学同人,26-52 (1997)

ページの先頭へ

特許等 : Patents

17.

Striga germination regulating agent and a stria germination control method using the same

Tsuchiya, Yuichiro; Uraguchi, Daisuke; Sathiyanarayanan, Arumugam Murugan; Hagihara, Shinya; Yoshimura, Masahiko; Kinoshita, Toshinori; Ooi, Takashi; Itami, Kenichiro

WO 2017002898 A1 20170105,名古屋大学,2016年6月30日出願

16.

ストライガ発芽調節剤

Striga germination regulating agent and a stria germination control method using the same

Tsuchiya, Yuichiro; Uraguchi, Daisuke; Sathiyanarayanan, A. M.; Kinoshita, Toshinori; Oi, Takashi

JP 2017014149 A 20170119,名古屋大学,2015年7月1日出願

15.

光学活性オキシインドール化合物の製造方法及びそれに触媒として用いられるトリアゾリウム塩

大井貴史、大松亨介

PCT/JP2016/054960, 名古屋大学, 2016年2月19日出願

14.

光学活性アルキルアミノスルホンアミド誘導体の製造方法及び光学活性β−アミノアルコール誘導体

Optically active β-aminoalcohols and their use for preparation of optically active alkylaminosulfonamides

Ooi, Takashi; Uraguchi, Daisuke

JP-A- JP-2013071892-2013-04-22,名古屋大学,三井化学(株),2011年9月26日出願

[特許]5757022

13.

Method for the preparation of optically active compound using chiral ammonium betaine

Ooi, Takashi; Uraguchi, Daisuke

JP-A- JP-2011190181-2011-09-29,名古屋大学

12.

Preparation of optically active arylaminophosphonium salt as catalyst for the asymmetric synthesis, and method for preparation of optically active β-aminonitroalkanes

Ooi, Takashi; Uraguchi, Daisuke

JP-A-2010209050-2010-09-24,三井化学(株),名古屋大学

11.

光学活性テトラアミノホスホニウム塩、不斉合成反応用触媒、不斉合成反応、及び四置換α-アミノ酸含有ペプチドの不斉合成方法

大井 貴史, 浦口 大輔

特開-2010-059133,2010年3月18日,三井化学(株),名古屋大学

10.

Chiral tetraaminophosphonium salts, catalyst for asymmetric synthesis and method for producing chiral beta-nitroalcohol

Ooi, Takashi; Uraguchi, Daisuke

US-A1-2009131716-2009-05-21,三井化学(株),名古屋大学

9.

Catalyst capable of allowing Strecker reaction to proceed stereoselectively and method for stereoselectively producing .alpha.-aminonitrile derivative using the same

T. Ooi, K. Maruoka

WO-A1-2007074553,2007年7月5日 長瀬産業株式会社,京都大学

8.

光学活性な3-ニトロアルキルマロン酸エステル誘導体の製造方法

丸岡 啓二,大井 貴史

特開2005-263664,2005年9月29日 長瀬産業株式会社

7.

光学活性な3-アミノアスパラギン酸誘導体の製造方法

丸岡 啓二,大井 貴史

特開2005-255610,2005年9月22日 長瀬産業株式会社

6.

光学活性なビシナルジアミンおよびその製造方法

丸岡 啓二,大井 貴史

特開2005-232103,2005年9月2日 長瀬産業株式会社

5.

光学活性3,5-ジヒドロ-4H-ジナフト[2,1-c:1’,2’-e]アゼピンおよびそのシュウ酸塩の製造方法

丸岡 啓二,大井 貴史,生中 雅也,奥田 佳朗

特開2005-15402,2005年1月20日 長瀬産業株式会社,ナガセケムテックス株式会社

4.

Quaternary ammonium bifluoride compound and process for producing chiral nitroalcohol

K. Maruoka, T. Ooi

WO-A1-2004076459,2004年9月10日 長瀬産業株式会社
特-4593289, 2010年9月24日

3.

Process for producing optically active .alpha.-substituted cysteine or salt thereof, intermediate therefor, and process for producing the same

K. Maruoka, T. Ooi, K. Inoue

WO-A1-2004031163,2004年4月15日 株式会社カネカ

2.

γ-ニトロカルボニル化合物の製造方法

丸岡 啓二,大井 貴史

特開2004-352708,2004年12月16日 長瀬産業株式会社

1.

軸不斉を有する光学活性な4級アンモニウム塩を相間移動触媒として用いるβ-ヒドロキシアミノ酸誘導体の製造方法

丸岡 啓二,大井 貴史

特-4217085,2009年1月28日発行 長瀬産業株式会社
特開-2003-327566, 2003年11月19日 2003年3月4日出願

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