Biography

Specialization

Coordination Chemistry / Solid State Chemistry / Supramolecular Chemistry / Organic Conductors

Memberships

• Chemical Society of Japan
• Coordination Chemistry Society
• Molecular Science Society
• Polymer Society of Japan
• The Physical Society of Japan

Awards

• 2020.1 29th Japan MRS Annual Meeting Encouragement Award (Japan MRS)
• 2016.4 CREST "Molecular Technology" 4th Rising Star Award
• 2008.9 58th Coordination Chemistry Discussion Group Poster Award (Coordination Chemistry Society)

Selected Publications

2022

An electrically conductive metallocycle: densely packed molecular hexagons with π-stacked radicals
M. Cui, R. Murase, Y. Shen, T. Sato, S. Koyama, K. Uchida, T. Tanabe, S. Takaishi, M. Yamashita, H. Iguchi,
Chem. Sci. , 2022 , in press
DOI: 10.1039/D2SC00447J,
Thermally Induced Electron-Hole Dissociation Dynamics in Quasi-One-Dimensional Bromo-Bridged Palladium(III) Mott-Insulator [Pd(en)2Br](Suc-Cn)2·H2O (Cn-Y = dialkylsulfosuccinate; n = 5 and 6)
S. Kumagai, H. Iguchi, M. Yamashita, S. Takaishi,
Phys. Chem. Chem. Phys. , 2022, 24, 7978-7982
DOI: 10.1039/D2CP00051B
Macro- and atomic-scale observations of a one-dimensional heterojunction in a nickel and palladium nanowire complex
M. Wakizaka, S. Kumagai, H. Wu, T. Sonobe, H. Iguchi, T. Yoshida, M. Yamashita, S. Takaishi,
Nature Commun , 2022, 13, 1188
DOI: 10.1038/s41467-022-28875-8, publication date: March 4, 2022
Bromine Vapor Induced Continuous p- to n-Type Conversion of Semiconductive Metal-Organic Framework Cu[Cu(pdt)2]
S. Gupta, H. Tanaka, T. Sato, S. Ye, B. K. Breedlove, H. Iguchi, S. Takaishi,
Inorg. Chem. , 2022 , 61 , 4414–4420
DOI: 10.1021/acs.inorgchem.1c03933, publication date: March 2, 2022
Charge-Density-Wave Amplitude in Quasi-one-dimensional Halogen-bridged Palladium Complex, [Pd(15N-en)2Br](Suc-C5)2·H2O (Suc-C5 = dipentylsulfosuccinate), Estimated by 15N Solid-state NMR.
S. Kumagai, H. Iguchi, M. Yamashita, S. Takeda, S. Takaishi,
Chem. Lett. , 2022 , 51 , 281-283
DOI: 10.1246/cl.210804, publication date: January 29, 2022
Elucidating 2D Charge-Density-Wave atomic structure in an MX-chain by the 3D-ΔPair Distribution Function method
L. Guérin, T. Yoshida, E. Zatterin, A. Simonov, D. Chernyshov, H. Iguchi, B. Toudic, S. Takaishi, M. Yamashita,
Chem. Phys. Chem. , 2022 , 23 , e202100857
DOI: 10.1002/cphc.202100857, publication date: January 27, 2022

Selected Publications Before 2022

Bluish Hydrochromic Naphthalenediimide Salt: Change of Hydrogen-Bond Interactions as the New Mechanism of Vapochromism
T. Tanabe, T. Sato, K. Fuku, K. Uchida, T. Yamauchi, S. Takaishi, H. Iguchi,
Chem. Lett. , 2021 , 50 , 1479–1482
DOI: 10.1246/cl.210275, publication date: May 28, 2021
Ionic Charge-Transfer Liquid Crystals Formed by Alternating Supramolecular Copolymerization of Liquid -Donors and TCNQ
H. Iguchi, H. Furutani, N. Kimizuka,
Front. Chem. , 2021 , 9 , 657246
DOI: 10.3389/fchem.2021.657246, publication date: March 29, 2021
Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes
S. Koyama, T. Tanabe, S. Takaishi, M. Yamashita, H. Iguchi,
Chem. Commun. , 2020 , 26 , 13109–13112
DOI: 10.1039/D0CC03541F, publication date: September 23, 2020
Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction
K. Fuku, M. Miyata, S. Takaishi, T. Yoshida, M. Yamashita, N. Hoshino, T. Akutagawa, H. Ohtsu, M. Kawano, H. Iguchi,
Chem. Commun. , 2020 , 56 , 8619–8622
DOI: 10.1039/D0CC03062G, publication date: June 22, 2020
Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers
L. Qu, H. Iguchi, S. Takaishi, F. Habib, C. F. Leong, D. M. D'Alessandro, T. Yoshida, H. Abe, E. Nishibori, M. Yamashita,
J. Am. Chem. Soc. , 2019 , 141 , 6802–6806
DOI: 10.1021/jacs.9b01717, publication date: April 17, 2019
Multiple-Hydrogen-Bond Approach to Uncommon Pd(III) Oxidation State: A Pd−Br Chain with High Conductivity and Thermal Stability
M. R. Mian, H. Iguchi, S. Takaishi, H. Murasugi, T. Miyamoto, H. Okamoto, H. Tanaka, S. Kuroda, B. K. Breedlove, M. Yamashita,
J. Am. Chem. Soc. , 2017 , 139, 6562–6565
DOI: 10.1021/jacs.7b02558, publication date: May 3, 2017
Photoresponsive Nanosheets of Polyoxometalates Formed by Controlled Self-Assembly Pathways
K. Ishiba, T. Noguchi, H. Iguchi, M. Morikawa, K. Kaneko, N. Kimizuka,
Angew. Chem. Int. Ed. , 2017 , 56 , 2974–2978
DOI: 10.1002/anie.201612473, publication date: February 15, 2017
Direct Observation of Ordered High-Spin–Low-Spin Intermediate States of an Iron(III) Three-Step Spin-Crossover Complex
Z.-Y. Li, H. Ohtsu, T. Kojima, J.-W. Dai, T. Yoshida, B. K. Breedlove, W.-X. Zhang, H. Iguchi, O. Sato, M. Kawano, M. Yamashita,
Angew. Chem. Int. Ed. , 2016 , 55 , 5184–5189
DOI: 10.1002/anie.201511281, publication date: March 17, 2016
Solid-State Electrochemistry of a Semiconducting MMX-Type Diplatinum Iodide Chain Complex
H. Iguchi, A. Nafady, S. Takaishi, M. Yamashita, A. M. Bond,
Inorg. Chem. , 2014 , 53 , 4022–4028
DOI: 10.1021/ic402980t, publication date: March 31, 2014
Controlling the Electronic States and Physical Properties of MMX-Type Diplatinum-Iodide Chain Complexes via Binary Countercations
H. Iguchi, S. Takaishi, B. K. Breedlove, M. Yamashita, H. Matsuzaki, H. Okamoto,
Inorg. Chem. , 2012 , 51 , 9967–9977
DOI: 10.1021/ic301469u, publication date: September 4, 2012
Water-Vapor-Induced Reversible Switching of Electronic States in a MMX-Type Chain Complex with Retention of Single Crystallinity
H. Iguchi, S. Takaishi, H. Miyasaka, M. Yamashita, H. Matsuzaki, H. Okamoto, H. Tanaka, S. Kuroda,
Angew. Chem. Int. Ed. , 2010 , 49 , 552–555
DOI: 10.1002/anie.200905608, publication date: December 10, 2009
Mixed Charge-Ordering State of MMX-Type Quasi-One-Dimensional Iodide-Bridged Platinum Complexes with Binary Countercations
H. Iguchi, S. Takaishi, T. Kajiwara, H. Miyasaka, M. Yamashita, H. Matsuzaki, H. Okamoto,
J. Am. Chem. Soc. , 2008 , 130 , 17668–17669
DOI: 10.1021/ja807901p, December 8, 2008