Member忍久保研の構成員
講師：福井 識人
Dr. Norihito Fukui
略歴
| 2013年3月 | 京都大学 理学部 卒業 |
|---|---|
| 2015年3月 | 京都大学大学院 理学研究科修士課程 修了 (指導教官：大須賀 篤弘 教授、依光 英樹 准教授（当時）） |
| 2015年4月–2018年3月 | 日本学術振興会特別研究員(DC1) |
| 2018年3月 | 京都大学大学院 理学研究科 博士後期課程 修了 (指導教官：大須賀 篤弘 教授） 博士（理学）取得 |
| 2018年4月–2022年3月 | 名古屋大学大学院 工学研究科 助教 |
| 2021年10月– | JSTさきがけ研究者「物質探索空間の拡大による未来材料の創製」領域１期生 |
| 2022年4月– | 名古屋大学大学院 工学研究科 講師 |
業績
| CV | |
|---|---|
| ORCiD | 0000-0002-0466-0116 |
| ResearcherID | N-6736-2018 |
| researchmap | 70823277 |
専門分野
有機化学、構造有機化学
原著論文
66. End-to-End Bent Perylene Bisimide Cyclophanes by Double Sulfur Extrusion
Y. Tanaka, K. Tajima, R. Kusumoto, Y. Kobori,* N. Fukui,* H. Shinokubo*
J. Am. Chem. Soc. 2024.
65. Homochiral and Heterochiral Self-Sorting Assemblies of Antiaromatic Ni(II) Norcorrole Dimers
S. Y. Liu, S. Li, S. Ukai, R. Nozawa, N. Fukui, R. Sugimori, R. Kishi, H. Shinokubo*
Chem. Eur. J. 2024, e202400292.
64. Changing aromatic properties through stacking: the face-to-face dimer of Ni(II) bis(pentafluorophenyl)norcorrole
Q. Wang, D. Sundholm,* J. Gauss, T. Nottoli, F. Lipparini, S. Kino, S. Ukai, N. Fukui, H. Shinokubo.
Phys. Chem. Chem. Phys. 2024.
63. Synthesis of sterically congested double helicene by alkyne cycloisomerization
J. Hirano, S. Miyoshi, E. Yashima, T. Ikai, H. Shinokubo, N. Fukui,*
Chem. Commun. 2024.
62. Close Stacking of Antiaromatic Ni(II) Norcorrole Originating from a Four-Electron Multicentered Bonding Interaction
S. Kino, S. Ukai, N. Fukui, R. Haruki, R. Kumai, Q. Wang, S. Horike, Q. M. Phung, D. Sundholm,* H. Shinokubo*
J. Am. Chem. Soc. 2024, 146, 9311-9317.
61. Excimer Formation Driven by Excited-State Structural Relaxation in a Covalent Aminonaphthalimide Dimer
R. Jing, Y. Li, K. Tajima, Y. Wan, N. Fukui,* H. Shinokubo,* Z. Kuang,* A. Xia*
J. Phys. Chem. Lett. 2024, 15, 1469-1476.
60. A Triply Linked Porphyrin−Norcorrole Hybrid with Singlet Diradical Character
K. Wang, S. Ito, S. Ren, D. Shimizu, N. Fukui, R. Kishi, Q. Liu,* A. Osuka, J. Song,* H. Shinokubo*
Angew. Chem. Int. Ed. 2024, e202401233.
59. Synthesis and properties of bay-functionalized 9,9′-bifluorenylidene derivatives
J. Hirano, H. Shinokubo, N. Fukui*
Chem. Lett. 2024, 53upad015.
58. Effect of Internal Substituents on the Properties of Dibenzo[g,p]chrysene
Y. Takeo, J. Hirano, N. Fukui,* H. Shinokubo*
Org. Lett. 2023, 25, 8484–8488.
57. Effect of internal oxygen substituents on the properties of bowl-shaped aromatic hydrocarbons
Y. Takeo, J. Hirano, D. Shimizu, N. Fukui,* H. Shinokubo*
Org. Chem. Front. 2023, 10, 5895–5901.
56. Intrinsic Photostability in Dithiolonaphthalimide Achieved by Disulfide Bond-Induced Excited-State Quenching
Z. Wang, R. Jing, Y. Li, D. Song, Y. Wan, N. Fukui,* H. Shinokubo,* Z. Kuang,* and A. Xia*
J. Phys. Chem. Lett. 2023, 14, 8485–8492.
55. Highly soluble Ni(II) dithienylnorcorrole
S. Itabuchi, R. Nozawa, T. Yoshida, N. Fukui, H. Shinokubo*
J. Porphyrins Phthalocyanines. 2023, 27, 121-125.
54. Easily Switchable 18π-, 19π-, and 20π-Conjugation of Diazaporphyrin Double-Pincer Bispalladium Complexes.
T. Sakurai, Y. Hiraoka, H. Tanaka, Y. Miyake, N. Fukui, H. Shinokubo*
Angew. Chem. Int. Ed. 2023, in press.
53. Near-Infrared-Responsive Hydrocarbons Designed by π-Extension of Indeno[1,2,3,4-pgra]perylene at the 1,2,12-Positions.
M. Kato, J. Kim, J. Oh, D. Shimizu, N. Fukui,* H. Shinokubo*
Chem. Eur. J. 2023, in press.
52. One-dimensional stacking array of 10,20-diphenyl-5,15-diazaporphyrin metal complexes.
S. Mori, T. Sakurai, T. Nishimura, N. Fukui, Y. Miyake,* H. Shinokubo*
J. Porphyrins Phthalocyanines. 2023, in press.
51. Dinaphthooxepine Bisimide Undergoes Oxygen Extrusion Reaction upon Electron Injection at Room Temperature
M. Odajima, N. Fukui,* H. Shinokubo*
Org. Lett. 2023, 25, 282–287.
50. Diazazethrene Bisimide: A Strongly Electron-Accepting π-System Synthesized via the Incorporation of both Imide Substituents and Imine-type Nitrogen Atoms into Zethrene
K. Tajima, K. Matsuo, H. Yamada, N. Fukui,* H. Shinokubo*
Chem. Sci. 2023, 14, 635-642.
49. Realization of Stacked-Ring Aromaticity in a Water-Soluble Micellar Capsule
S. Liu, N. Kishida, J. Kim, N. Fukui, R. Haruki, Y. Niwa, R. Kumai, D. Kim,* M. Yoshizawa,* H. Shinokubo*
J. Am. Chem. Soc. 2023, 145, 2135-2141.
48. Planarization of a bowl-shaped molecule by triple-decker stacking
H. Kawashima, N. Fukui, Q. M. Phung,* T. Yanai, H. Shinokubo*
Cell. Rep. Phys. Sci. 2022, 3, 101045
47. D-Mannose-appended 5,15-diazaporphyrin for photodynamic therapy
L. M. A. Ali, K. Miyagawa, N. Fukui, M. Onofre, K. Elcheikh, A. Morère, S. Clément, M. Gary-Bobo,* S. Richeter,* H. Shinokubo*
Org. Biomol. Chem. 2022, 20, 8217-8222
46. Gram-Scale Diversity-Oriented Synthesis of Dinaphthothiepine Bisimides as Soluble Precursors for Perylene Bisimides
Y. Tanaka, K. Matsuo,* H. Yamada,* N. Fukui,* H. Shinokubo*
Eur. J. Org. Chem. 2022, 31, e202200770.
45. Symmetry-breaking charge separation in a nitrogen-bridged naphthalene monoimide dimer
X. Niu, K. Tajima, J. Kong, M. Tao, N. Fukui,* Z. Kuang,* H. Shinokubo,* A.Xia*
Phys. Chem. Chem. Phys. 2022, 24, 14007-14015
44. Nitrogen Extrusion of Diazacorrphycenes to Azacorroles and Synthesis of Two Types of Copper 10-Azacorrole Complexes
A.Yagi, N. Okada, N. Fukui, H. Tanaka, T. Hatakeyama, H. Shinokubo*
Chem. Lett. 2022, 51, 321-324
43. Synthesis of Dibenzo[h,t]rubicene through Its Internally Dimethoxy-Substituted Precursor
M. Kato, N. Fukui,* H. Shinokubo*
Chem. Lett. 2022, 51, 288-291
42. Isolation and Structure Analysis of a Ni(II) Norcorrole Radical Anion
S. Ukai, N. Fukui, T. Ikeue, H. Shinokubo*
Chem. Lett. 2022, 51, 181-184
41. A Supramolecular Polymer Constituted of Antiaromatic Ni(II) Norcorroles
S. Ukai, A. Takamatsu, M. Nobuoka, Y. Tsutsui, N. Fukui, S. Ogi,* S. Seki,* S. Yamaguchi,* H, Shinokubo*
Angew. Chem. Int. Ed. 2022, 61, e202114230.
40. Indeno[1,2,3,4-pqra]perylene: A Medium-Sized Aromatic Hydrocarbon Exhibiting Full-Range Visible-Light Absorption
M. Kato, N. Fukui,* H, Shinokubo*
Chem. Eur. J. 2022, 28, e202103647.
39. Antiaromatic 1,5-Diaza-s-indacenes
K. Hanida, J. Kim, N. Fukui, Y. Tsutsui, S. Seki,* D. Kim,* H. Shinokubo*
Angew. Chem. Int. Ed. 2021, 20765-20770.
38. Determinant Factors of Three-Dimensional Aromaticity in Antiaromatic Cyclophanes
H. Kawashima, S. Ukai, R. Nozawa, N. Fukui, G. Fitzsimmons, T. Kowalczyk,* H. Fliegl,* H. Shinokubo*
J. Am. Chem. Soc. 2021, 143, 10676−10685.
37. Non-Planar Perylene Bisimide Analogues with Inserted Carbonyl and Methylene Subunits
M. Odajima, K. Tajima, N. Fukui,* H. Shinokubo*
Angew. Chem. Int. Ed. 2021, 60, 15838−15843.
36. Acridino[2,1,9,8‐klmna]acridine Bisimides: An Electron‐Deficient π‐System for Robust Radical Anions and n‐Type Organic Semiconductors
K. Tajima, K. Matsuo, H. Yamada,* S. Seki,* N. Fukui,* H. Shinokubo*
Angew. Chem. Int. Ed. 2021, 60, 14060−14067.
35. Synthesis and Properties of an 18π Aromatic Norcorrole P(V) Complex
T. Yoshida, S. A. Shafie, H. Kawashima, N. Fukui, H. Shinokubo*
Org. Lett. 2021, 23, 2826–2830.
34. Redox-induced reversible [2+2] cycloaddition of an etheno-fused diporphyrin
K. Miyagawa, I. Hisaki, N. Fukui, H. Shinokubo*
Chem. Sci. 2021, 12, 5224–5229.
33. Dinaphtho[1,8-bc:1',8'-fg][1,5]dithiocine Bisimide
Y. Tanaka, K. Tajima, N. Fukui,* H. Shinokubo*
Asian J. Org. Chem. 2021, 10, 541–544.
32. Dual Emission of a Free‐Base 5‐Oxaporphyrinium Cation from its cis‐ and trans‐NH Tautomers
A. Takiguchi, S. Kang, N. Fukui,* D. Kim,* H. Shinokubo*
Angew. Chem. Int. Ed. 2021, 64, 2915–2919.
31. Synthesis and electron-transport property of stable antiaromatic NiII norcorrole with the smallest meso-substituent
S. Ukai, Y. Hee Koo, N. Fukui, S. Seki,* H. Shinokubo*
Dalton Trans. 2020, 49, 14383–14387.
30. as-Indaceno[3,2,1,8,7,6-ghijklm]terrylene as a near-infrared absorbing C70-fragment
Y. Tanaka, N. Fukui,* H. Shinokubo*
Nat. Commun. 2020, 11, 3873.
Press Release (English, EurekAlert!)
Press Release (English)
Highlighted in Synfacts
Editors’ Highlights
29. Dinaphthothiepine Bisimide and Its Sulfoxide: Soluble Precursors for Perylene Bisimide
S. Hayakawa, K. Matsuo, H. Yamada,* N. Fukui,* H. Shinokubo*
J. Am. Chem. Soc. 2020, 142, 11663−11668.
Highlighted in a newspaper（日刊工業新聞）
Highlighted in Synfacts
explanatory video (Japanese)
28. A 2-to-2′ 18-to-18′ doubly linked Ni(ii) norcorrole dimer: an effectively conjugated antiaromatic dyad
S.-Y. Liu, H. Kawashima, N. Fukui, H. Shinokubo*
Chem. Commun. 2020, 56, 6846−6849.
27. Reactions of Antiaromatic Norcorrole Ni(II) Complex with Carbenes
S.-Y. Liu, T. Fukuoka, N. Fukui, J.-Y. Shin, H. Shinokubo*
Org. Lett. 2020, 22, 4400–4403.
26. Synthesis and properties of 5-aza-15-thiaporphyrins
D. Yamashita, H. Omori, N. Fukui, H. Shinokubo*
J. Porphyr. Phthalocyanines. 2020, 24, 84−89.
25. Inserting Nitrogen: An Effective Concept to Create Nonplanar and Stimuli-Responsive Perylene Bisimide Analogues
S. Hayakawa, A. Kawasaki, Y. Hong, D. Uraguchi, T. Ooi, D. Kim,* T. Akutagawa,* N. Fukui,* H. Shinokubo*
J. Am. Chem. Soc. 2019, 141, 19807−19816.
Press Release (Japanese)
24. Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers
K. Tajima, N. Fukui,* H. Shinokubo*
Org. Lett. 2019, 21, 9516−9520.
23. 5,5,15,15-Tetraoxo-5,15-Dithiaporphyrinas a Highly Electron-Deficient Porphyrinic Ligand
A. Yagi, T. Kondo, D. Yamashita, N. Wachi, H. Omori, N. Fukui, T. Ikeue, H. Shinokubo*
Chem. Eur. J. 2019, 25, 15580−15585.
22. Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins
A. Takiguchi, N. Fukui, H. Shinokubo,*
Org. Lett. 2019, 21, 3950-3953.
21. Synthesis of meso‐Alkyl‐Substituted Norcorrole Ni(II) Complexes and Conversion to 5‐Oxaporphyrins(2.0.1.0)
S. Liu, H. Tanaka, R. Nozawa, N. Fukui, H. Shinokubo*
Chem. Eur. J. 2019, 25, 7618-7622.
Selected as a Hot Paper
20. Macroscopically Anisotropic Structures Produced by Light-induced Solvothermal Assembly of Porphyrin Dimers)
Y. Yamamoto, Y. Nishimura, S. Tokonami, N. Fukui, T. Tanaka, A. Osuka, H. Yorimitsu, and T. Iida
Sci. Rep. 2018, 8, 11108.
19. Diarylamine-Fused Subporphyrins: Proof of Twisted Intramolecular Charge Transfer (TICT) Mechanism
Koki Kise, Yongseok Hong, Norihito Fukui, Daiki Shimizu, Dongho Kim,* and Atsuhiro Osuka*
Chem. Eur. J. 2018, 24, 8306–8310.
18. Singly and Doubly Sulfone-inserted Porphyrin Arch-Tape Dimers
Norihito Fukui and Atsuhiro Osuka*
Bull. Chem. Soc. Jpn. 2018, 91, 1131–1137.
Selected as a BCSJ Award Article
17. Singly and Doubly 1,2-Phenylene-Inserted Porphyrin Arch-Tape Dimers: Synthesis and Highly Contorted Structures
Norihito Fukui and Atsuhiro Osuka*
Angew. Chem. Int. Ed. 2018, 57, 6304–6308.
16. Metalation Control of Open-shell Character in meso-meso Linked Porphyrin meso-Oxy Radical Dimers
Yuta Jun-i, Norihito Fukui, Ko Furukawa,* and Atsuhiro Osuka*
Chem. Eur. J. 2018, 24, 1528–1532.
15. A meso-meso β-β β-β Triply Linked Subporphyrin Dimer
Yasuhiro Okuda, Norihito Fukui, Jinseok Kim, Hua-Wei Jiang, Graeme Copley, Masaaki Kitano, Dongho Kim,* and Atsuhiro Osuka*
Angew. Chem. Int. Ed. 2017, 56, 12317–12321.
14. Porphyrin Arch-Tapes: Synthesis, Contorted Structures, and Full Conjugation
Norihito Fukui, Taeyon Kim, Dongho Kim,* and Atsuhiro Osuka*
J. Am. Chem. Soc. 2017, 139, 9075–9088.
Selected as a JACS Spotlight
Highlighted in Synfacts
13. Diphenylphosphine-Oxide-Fused and Diphenylphosphine-Fused Porphyrins: Synthesis, Tunable Electronic Properties, and Formation of Cofacial Dimers
Keisuke Fujimoto, Yuko Kasuga, Norihito Fukui, and Atsuhiro Osuka*
Chem. Eur. J. 2017, 23, 6741–6745.
12. Aromatic Metamorphosis of Dibenzofurans into Triphenylenes Starting with Nickel-Catalyzed Ring-Opening C-O Arylation
Yuto Kurata, Sinya Otsuka, Norihito Fukui, Keisuke Nogi, Hideki Yorimitsu,* and Atsuhiro Osuka
Org. Lett. 2017, 19, 1274–1277.
11. meso-to-meso PtII-bridged NiII-porphyrin dimers
Norihito Fukui, Hua-Wei Jiang, and Atsuhiro Osuka*
Org. Chem. Front. 2017, 4, 767–772.
10. Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations
Norihito Fukui, Wonhee Cha, Daiki Shimizu, Juwon Oh, Ko Furukawa,* Hideki Yorimitsu,* Dongho Kim,* and Atsuhiro Osuka*
Chem. Sci. 2017, 8, 189–199.
Highlighted in Synfacts
9. meso-meso Linked Diarylamine-Fused Porphyrin Dimers
Norihito Fukui, Hideki Yorimitsu,* and Atsuhiro Osuka*
Chem. Eur. J. 2016, 22, 18476–18483.
8. Pictet–Spengler Synthesis of Quinoline-Fused Porphyrins and Phenanthroline-Fused Diporphyrins
Ke Gao, Norihito Fukui, Seok Il Jung, Hideki Yorimitsu,* Dongho Kim,* and Atsuhiro Osuka*
Angew. Chem. Int. Ed. 2016, 55, 13038–13042.
Highlighted in Synfacts
7. Regioselective phenylene-fusion reactions of Ni(II)-porphyrins controlled by an electron-withdrawing meso-substituent
Norihito Fukui, Seung-Kyu Lee, Kenichi Kato, Daiki Shimizu, Takayuki Tanaka, Sangsu Lee, Hideki Yorimitsu,* Dongho Kim,* and Atsuhiro Osuka*
Chem. Sci. 2016, 7, 4059–4066.
6. meso,β-Oligohaloporphyrins as Useful Synthetic Intermediates of Diphenylamine-Fused Porphyrin and meso-to-meso β-to-β Doubly Butadiyne-Bridged Diporphyrin
Norihito Fukui, Hideki Yorimitsu,* and Atsuhiro Osuka*
Angew. Chem. Int. Ed. 2015, 54, 6311–6314.
5. Palladium-Catalyzed [3+2] Annulation of meso-Bromoporphyrin with Silylacetylenes and Desilylation of 8a-Silyl-7,8-dehydropurpurin
Norihito Fukui, Seiji Arai, Hiroshi Shinokubo, Hideki Yorimitsu,* and Atsuhiro Osuka*
Heterocycles 2015, 90, 252–260.
4. Control of the conformational dynamics of meso-meso vinylene-bridged Zn(II) porphyrin dimers through diamine coordination
Minjung Son, Young Mo Sung, Sumito Tokuji, Norihito Fukui, Hideki Yorimitsu, Atsuhiro Osuka,* and Dongho Kim*
Chem. Commun. 2014, 50, 3078–3080.
3. Synthesis of 7,8-Dehydropurpurin Dimers and Their Conversion into Conformationally Constrained β-to-β Vinylene-Bridged Porphyrin Dimers
Norihito Fukui, Hideki Yorimitsu,* Jong Min Lim, Dongho Kim,* and Atsuhiro Osuka*
Angew. Chem. Int. Ed. 2014, 53, 4395–4398.
2. Amination of meso-Bromoporphyrins and 9-Haloanthracenes with Diarylamines Catalyzed by a Palladium–PEPPSI Complex
Yuko Suzuki, Norihito Fukui, Kei Murakami, Hideki Yorimitsu,* and Atsuhiro Osuka*
Asian J. Org. Chem. 2013, 2, 1066–1071.
Selected as the Front Cover
1. Oxidative Fusion Reactions of meso-(Diarylamino)porphyrins
Norihito Fukui, Won-Young Cha, Sangsu Lee, Sumito Tokuji, Dongho Kim,* Hideki Yorimitsu,* and Atsuhiro Osuka*
Angew. Chem. Int. Ed. 2013, 52, 9728–9732.
著書・総説
3. ポルフィリン類の直接官能基化
福井 識人、忍久保 洋
直接的芳香族カップリング反応の設計と応用（監修：三浦雅博、平野康次）、14章 2019, シーエムシー出版
2. Organic Transformations by the Hydrosilane-Alkoxide System
Norihito Fukui
J. Synth. Org. Chem. Jpn. 2019, 77, 512–513.
1. Embedding heteroatoms: an effective approach to create porphyrin-based functional materials
Norihito Fukui, Keisuke Fujimoto, Hideki Yorimitsu, and Atsuhiro Osuka*
Dalton Trans. 2017, 46, 13322–13341.
