超分子設計学グループ酒田研究室 名古屋大学大学院 工学研究科 応用物質化学専攻

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研究成果

原著論文・総説

  1. Shigehisa Akine, Masato Nakano, Yoko Sakata, Sachiko Yano
    “Preferential Formation of Three-layered Host–Guest Complexes of a Planar Dinuclear Metallohost with Alkali Metal Ions”
    Chem. Eur. J. 2024, e202403071.
  2. Yoko Sakata, Seiya Kobayashi, Misato Yamamoto, Katsuya Doken, Mayu Kamezawa, Sachiko Yamaki, Shigehisa Akine
    “Non-threaded and rotaxane-type threaded wheel–axle assemblies consisting of dinickel(II) metallomacrocycle and dibenzylammonium axle”
    Commun. Chem. 2024, 7, 166.
  3. Satoshi Muratsugu, Kana Sawaguchi, Takafumi Shiraogawa, Shunsuke Chiba, Yoko Sakata, Sora Shirai, Hiroshi Baba, Masahiro Ehara, Shigehisa Akine, Mizuki Tada
    “Induced chirality at the surface: fixation of a dynamic M/P invertible helical Co3 complex on SiO2“
    Chem. Commun. 2024, 60, 2094–2097.
  4. Yoko Sakata, Ryosuke Nakamura, Toshihiro Hibi, Shigehisa Akine
    “Speed Tuning of the Formation/Dissociation of a Metallorotaxane”
    Angew. Chem. Int. Ed. 2023, e202217048.
  5. Yoko Sakata
    “Creation of Kinetically-Controlled Supramolecular Systems Based on Coordination Chemistry”
    J. Incl. Phenom. Macrocycl. Chem. 2023, 130, 161-188.
  6. Shigehisa Akine, Keisuke Nomura, Mizuho Takahashi, Yoko Sakata, Taizo Mori, Waka Nakanishi, Katsuhiko Ariga
    “Synthesis of amphiphilic chiral salen complexes and their conformational manipulation at the air-water interface”
    Dalton. Trans. 2023, 52, 260-268.
  7. Yoko Sakata, Shunsuke Chiba, and Shigehisa Akine
    “Transient Chirality Inversion during Racemization of Helical Cobalt(III) Complex ”
    Proc. Natl. Acad. Sci. U.S.A. 2022, 119, e2113237119.
  8. Katsuto Onishi, Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Yoko Sakata, Shigehisa Akine, Moe Ogasawara, Hitoshi Asakawa, Shunsaku Nagano, Yoshinori Takashima, Motohiro Mizuno, and Tomoki Ogoshi
    “State- and water repellency-​controllable molecular glass of pillar[5]arenes with fluoroalkyl groups by guest vapors”
    Chem. Sci. 2022, 13, 4082-4087.
  9. Shiori Sakamoto, Tsuyoshi Taniguchi, Yoko Sakata, Shigehisa Akine, Tatsuya Nishimura, and Katsuhiro Maeda
    “Synthesis of Pentaarylcyclobutenylrhodium(I) Complexes and Their Reactivity and Initiation Mechanism in Polymerization of Monosubstituted Acetylenes”
    Organometallics. 2022, 41, 472-479.
  10. Shiori Sakamoto, Tsuyoshi Taniguchi, Yoko Sakata, Shigehisa Akine, Tatsuya Nishimura, and Katsuhiro Maeda
    “Rhodium(I) Complexes Bearing an Aryl-Substituted 1,3,5-Hexatriene Chain: Catalysts for Living Polymerization of Phenylacetylene and Potential Helical Chirality of 1,3,5-Hexatrienes”
    Angew. Chem. Int. Ed. 2021, 60, 22201-22206.
  11. Yoko Sakata, Ryo Tsuyuki, Shingo Sugimoto, and Shigehisa Akine
    “Metal-dependent selective formation of calix[4]arene assemblies based on dynamic covalent chemistry”
    Chem. Commun. 2021, 57, 13510-13513. (highlighted as the outside back cover)
  12. Yoko Sakata, Masahiro Okada, and Shigehisa Akine
    “Guest Recognition Control Accompanied by Stepwise Gate-Closing and Opening of a Macrocyclic Metallohost”
    Chem. Eur. J. 2021, 27, 2284-2288. (highlighted as the inside front cover)
  13. Sk Asif Ikbal, Yoko Sakata, and Shigehisa Akine
    “A chiral spirobifluorene-based bis(salen) zinc(II) receptor towards highly enantioselective binding of chiral carboxylates”
    Dalton Trans. 2021, 50, 4119-4123. (highlighted as the back cover)
  14. Tomoki Ogoshi, Yukie Hamada, Ryuta Sueto, Ryosuke Kojima, Fumiyasu Sakakibara, Yuuya Nagata, Yoko Sakata, Shigehisa Akine, Toshikazu Ono, Takahiro Kakuta, and Tada-aki Yamagishi
    “Vapoluminescence Behavior Triggered by Crystal-State Complexation between Host Crystals and Guest Vapors Exhibiting No Visible Fluorescence”
    Cryst. Growth Des. 2020, 20, 7087-7092. (highlighted as a Supplementary Journal Cover)
  15. Yoko Sakata, Takaya Ogura, and Shigehisa Akine
    “Efficient formation of [3]pseudorotaxane based on cooperative complexation of dibenzo-24-crown-8 with diphenylviologen axle”
    Chem. Commun. 2020, 56, 8735-8738. (published in Emerging Investigators themed issue 2020)
  16. Yoko Sakata, Masahiro Okada, Munehiro Tamiya and Shigehisa Akine
    “Post-Metalation Modification of Macrocyclic Dicobalt(III) Metallohost by Site-Selective Ligand Exchange for Guest Recognition Control”
    Chem. Eur. J. 2020, 26, 7595-7601. (highlighted as the inside front cover)
  17. Shizin Fa, Yoko Sakata, Shigehisa Akine, and Tomoki Ogoshi.
    “Non-Covalent Interactions Enable the Length-Controlled Generation of Discrete Tubes Capable of Guest Exchange”
    Angew. Chem. Int. Ed. 2020, 59, 9309-9313.
  18. Shigehisa Akine, and Yoko Sakata
    “Control of Guest Binding Kinetics in Macrocycles and Molecular Cages”
    Chem. Lett. 2020, 49, 428-441. (Highlight Review)
  19. Massimo Cametti, Yoko Sakata, Javier Marti-Rujas, and Shigehisa Akine
    “ON/OFF Control of the Flipping Motion of di-Uranyl bis-(Salophen) Macrocycle by Extremely Strong Binding with Fluoride Ion”
    Inorg. Chem. 2019, 58, 14871-14875.
  20. Yoko Sakata, Munehiro Tamiya, Masahiro Okada, and Shigehisa Akine
    “Switching of Recognition First and Reaction First Mechanisms in Host-Guest Binding Associated with Chemical Reactions”
    J. Am. Chem. Soc. 2019, 141, 15597-15604. (highlighted as a Supplementary Journal Cover)
  21. Yoko Sakata, Yoshiki Furukawa, and Shigehisa Akine
    “Functionalized metallonanobelt derivatives having quinoxaline scaffold prepared from a common precursor”
    Tetrahedron Lett. 2019, 60, 2049-2053. (highlighted as a front cover)
  22. Tomoki Ogoshi, Ryuta Sueto, Masafumi Yagyu, Ryosuke Kojima, Takahiro Kakuta, Tada-aki Yamagishi, Kazuki Doitomi, Anil Tummanapelli, Hajime Hirao, Yoko Sakata, Shigehisa Akine, and Motohiro Mizuno
    “Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels”
    Nature Commun. 2019, 10, 479.
  23. Yoko Sakata, Shunsuke Chiba, Masato Miyashita, Tatsuya Nabeshima, and Shigehisa Akine
    “Ligand Exchange Strategy for Tuning of Helicity Inversion Speeds of Dynamic Helical Tri(saloph) Metallocryptands”
    Chem. Eur. J. 2019, 25, 2962-2966. (highlighted as a cover picture)
  24. Tomoki Ogoshi, Yukie Hamada, Ryuta Sueto, Yoko Sakata, Shigehisa Akine, Adhitya Mangala Purta Moeljadi, Hajime Hirao, Takahiro Kakuta, and Tada-aki Yamagishi
    “Host–Guest Complexation Using Pillar[5]arene Crystals: Crystal‐Structure Dependent Uptake, Release, and Molecular Dynamics of an Alkane Guest”
    Chem. Eur. J. 2019, 25, 2497-2502.(highlighted as a cover picture)
  25. Mio Sekino, Hideki Furutachi, Kyosuke Tasaki, Takanao Ishikawa, Shuhei Fujinami, Shigehisa Akine, Yoko Sakata, Masatatsu Suzuki, Takashi Nomura, Takashi Ogura, and Teizo Kitagawa
    “Crystal Structure of Bis(μ-hydroxo)diiron(II) Complex with a Dinucleating Ligand Having a Butyl Linker”
    X-ray Struct. Anal. Online. 2019, 35, 5-7.
  26. Yoko Sakata, Ryoichi Yamamoto, Daiki Saito, Yuko Tamura, Keisuke Maruyama, Tomoki Ogoshi, and Shigehisa Akine
    “Metallonanobelt: A Kinetically Stable Shape-Persistent Molecular Belt Prepared by Reversible Self-Assembly Processes”
    Inorg. Chem. 2018, 57, 15500-15506. (highlighted as a Supplementary Journal Cover)
  27. Takahiro Soeta, Nobuhiro Ohashi, Toshiharu Kobayashi, Yoko Sakata, Takuya Suga, and Yutaka Ukaji
    “Synthesis of Sterically Fixed Phytochrome Chromophore Derivatives Bearing a 15E-Fixed or 15E-Anti-Fixed CD-Ring Component”
    J. Org. Chem. 2018, 83, 10743-10748.
  28. Mio Sekino, Hideki Furutachi, Rina Tojo, Ayumi, Kishi, Hanako Kajiwara, Takatoshi Suzuki, Kaito Suzuki, Shuhei Fujinami, Shigehisa Akine, Yoko Sakata, Takehiro Ohta, Shinya Hayami, and Masatatsu Suzuki
    “New mechanistic insight into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(III) complex”
    Chem. Commun. 2017, 53, 8838-8841. (Highlight as an inside front cover, featured as a HOT Article for July 2017)
  29. Yoko Sakata, Chiho Murata, and Shigehisa Akine
    “Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange”
    Nature Commun. 2017, 8, 16005.
  30. Tomoki Ogoshi, Ryuta Sueto, Yukie Hamada, Kazuki Doitomi, Hajime Hirao, Yoko Sakata, Shigahisa Akine, Takahiro Kakuta, and Tada-aki Yamagishi
    “Alkane-length sorting using activated pillar[5]arene crystals”
    Chem. Commun. 2017, 53, 8577-8580.
  31. Yoko Sakata, Seiya Kobayashi, and Shigehisa Akine
    “Two-step modulation of ion recognition using a bis(saloph)-macrocyclic host having a 24-crown-8-like cavity”
    Chem. Commun. 2017, 53, 6363-6366.
  32. Tomoki Ogoshi, Yasuo Shimada, Yoko Sakata, Shigehisa Akine, and Tada-aki Yamagishi
    “Alkane-Shape-Selective Vapochromic Behavior Based on Crystal-State Host-Guest Complexation of Pillar[5]arene Containing One Benzoquinone Unit”
    J. Am. Chem. Soc. 2017, 139, 5664-5667.
  33. Takahiro Soeta, Akihiro Matsumoto, Yoko Sakata, and Yutaka Ukaji
    “Development of a One-Pot Synthetic Method for Multifunctional Oxazole Derivatives Using Isocyanide Dichloride”
    J. Org. Chem. 2017, 82, 4930-4935.
  34. Takahiro Soeta, Suguru Takashita, Yoko Sakata, and Yutaka Ukaji
    “Ugi-type Multicomponent Reaction of Nitrile Imines, Isocyanides, and Isocyanates: Effective Synthesis of 1,2,4-Triazinedione Derivatives”
    Asian J. Org. Chem. 2016, 5, 1041-1047.
  35. Yoko Sakata, Satomi Fukushima, Shigehisa Akine, and Jun-ichiro Setsune
    “Solvent-Dependent Dual-Mode Photochromism between T- and P-Types in a Dipyrrinone Derivative”
    Chem. Commun. 2016, 52, 1278-1281.
  36. Mio Sekino, Hideki Furutachi, Kyosuke Tasaki, Takanao Ishikawa, Shigeki Mori, Shuhei Fujinami, Shigehisa Akine, Yoko Sakata, Takashi Nomura, Takashi Ogura, Teizo Kitagawa, and Masatatsu Suzuki
    “New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands”
    Dalton. Trans. 2016, 45, 469-473.
  37. Takahiro Soeta, Suguru Takashita, Yoko Sakata, Yutaka Ukaji
    “Phosphinic Acid-Promoted Addition Reaction of Isocyanides to (Z)-Hydroximoyl Chlorides: Efficient Synthesis of α-(Hydroxyimino)amides”
    Org. Biomol. Chem. 2016, 14, 694-700.
  38. Tomoki Ogoshi, Ryuta Sueto, Kumiko Yoshikoshi, Yoko Sakata, Shigehisa Akine, and Tada-aki Yamagishi
    “Host-Guest Complexation of Perethylated Pillar[5]arene with Alkanes in the Crystal State”
    Angew. Chem. Int. Ed. 2015, 54, 9849-9852.
  39. Tomohiro Tsugawa, Hideki Furutachi, Megumi Marunaka, Taichi Endo, Koji Hashimoto, Shuhei Fujinami, Shigehisa Akine, Yoko Sakata, Shigenori Nagatomo, Takehiko Tosha, Takashi Nomura, Teizo Kitagawa, Takashi Ogura, and Masatatsu Suzuki
    “Oxidation Reactivity of a Structurally and Spectroscopically Well-Defined Mononuclear Peroxocarbonate-Iron(III) Complex”
    Chem. Lett. 2015, 44, 330-332.
  40. Mio Kondo, Shuhei Furukawa, Kenji Hirai, Takaaki Tsuruoka, Julien Reboul, Hiromitsu Uehara, Stephane Diring, Yoko Sakata, Osami Sakata, and Susumu Kitagawa
    “Trapping of a Spatial Transient State During the Framework Transformation of a Porous Coordination Polymer”
    J. Am. Chem. Soc. 2014, 136, 4938-4944.
  41. Shuhei Furukawa, Yoko Sakata, and Susumu Kitagawa,
    “Control over Flexibility of Entangled Porous Coordination Frameworks by Molecular and Mesoscopic Chemistries”
    Chem. Lett. 2013, 42, 570-576. (Highlight Review)
  42. Kenji Hirai, Kebi Chen, Tomohiro Fukushima, Satoshi Horike, Mio Kondo, Nicolas Louvain, Chiwon Kim, Yoko Sakata, Mikhail Meilikhov, Osami Sakata, Susumu Kitagawa, and Shuhei Furukawa
    “Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals”
    Dalton Trans. 2013, 42, 15868-15872.
  43. Yoko Sakata, Shuhei Furukawa, Mio Kondo, Kenji Hirai, Nao Horike, Yohei Takashima, Hiromitsu Uehara, Nicolas Louvain, Mikhail Meilikhov, Takaaki Tsuruoka, Seiji Isoda, Wataru Kosaka, Osami Sakata, and Susumu Kitagawa
    “Shape-Memory Nanopores Induced in Coordination Frameworks by Crystal Downsizing”
    Science 2013, 339, 193-196.
  44. Yoko Sakata, Shuhei Furukawa, Chiwon Kim, and Susumu Kitagawa
    “Formation of Nanocrystals of a Zinc Pillared–layer Porous Coordination Polymer Using Microwave–assisted Coordination Modulation”
    Chem. Lett. 2012, 41, 1436-1438. (selected as Editor’s Choice)
  45. Kenji Hirai, Shuhei Furukawa, Mio Kondo, Mikhail Meilikhov, Yoko Sakata, Osami Sakata, and Susumu Kitagawa
    “Targeted Functionalisation of a Hierarchically-Structured Porous Coordination Polymer Crystal Enhances Its Entire Function”
    Chem. Commun. 2012, 48, 6472-6474. (highlighted as a cover picture)
  46. Manuel Tsotsalas, Ayako Umemura, Franklin Kim, Yoko Sakata, Julien Reboul, Susumu Kitagawa, and Shuhei Furukawa
    “Crystal Morphology-Directed Framework Orientation in Porous Coordination Polymer Films and Freestanding Membranes via Langmuir-Blodgettry”
    J. Mater. Chem. 2012, 22, 10159-10165. (highlighted as a cover picture)
  47. Yoko Sakata, Shuichi Hiraoka, and Mitsuhiko Shionoya
    “Site-Selective Ligand Exchange on a Heteroleptic Ti(IV) Complex towards Stepwise Multicomponent Self-Assembly”
    Chem. Eur. J. 2010, 16, 3318-3325. (highlighted as a frontispiece)
  48. Shuichi Hiraoka, Yoko Sakata, and Mitsuhiko Shionoya
    “Ti(IV)–Centered Dynamic Interconversion between Pd(II), Ti(IV)–Containing Ring and Cage Molecules”
    J. Am. Chem. Soc. 2008, 130, 10058-10059.

解説・著書

  1. 酒田陽子, 秋根茂久
    “逐次的な認識メカニズムでホスト-ゲスト化学を制御する”
    超分子研究会アニュアルレビュー, 2022, 42, 2-3.
  2. 酒田陽子
    “速度論的制御に基づく新奇機能性超分子錯体の開拓”
    Bull. Jpn. Soc. Coord. Chem. 2021, 77, 26-36. (award account)
  3. 酒田陽子
    “速度論的制御に基づく超分子金属錯体の化学”
    高分子, 2021, Vol.70, No. 4,187-191.
  4. 酒田陽子, 秋根茂久
    “開閉できる応答性超分子の設計とその応用展開”
    次世代のポリマー・高分子開発、新しい用途展開と将来展望, 138-149. 2019,
    （株）技術情報協会
  5. 秋根茂久, 酒田陽子, 塩谷光彦
    “分子サイズの動く機械を組み立てる”
    現代化学, No 549, 29-32, 2016.
  6. 酒田陽子
    “光を当てると溶ける多孔性結晶”
    化学, Vol.71 No. 4, 68-69, 2016.
  7. 酒田陽子
    “Ti(IV)イオンの配位構造変化と連動したかご型および環状Ti(IV)–Pd(II)多核錯体間における動的相互変換”
    Bull. Jpn. Soc. Coord. Chem., 51, 84-87, 2008. (award account)
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