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原著論文（2024 / 2023 / 2022 / 2021 / 2020 / 2019 / 2018 / 2017 / 2016 / 2015 / 2014 / 2013 / 2012 / 2011 / 2010 / 2009 / 2008–2006 / 2005–2003 / 2002–1998 / 1997–1993）、 書著・総説

原著論文（2002–1998年）

2002

  • Triethylborane-Induced Radical Reaction of Alkynylgallium with α-Halo Carbonyl Compounds
    S.-I. Usugi, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Bull. Chem. Soc. Jpn. 2002, 75, 2687-2690.

  • Preparation of Allylic Germanes with Tri(2-furyl)germane via π-Allylpalladium Species
    H. Kinoshita, H. Shinokubo, and K. Oshima
    Synlett 2002, 1916-1918.

  • Triethylborane-Induced Radical Reaction of Gallium Enolates with α-Halo Esters
    S.-I. Usugi, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Bull. Chem. Soc. Jpn. 2002, 75, 2049-2052.

  • Biaryl Synthesis from Two Different Aryl Halides with Tri(2-furyl)germane
    T. Nakamura, H. Kinoshita, H. Shinokubo, and K. Oshima
    Org. Lett. 2002, 4, 3165-3167.

  • Intramolecular Tandem Michael-Type Addition/Aldol Cyclization Induced by TiCl4-R4NX Combinations
    K. Yagi, T. Tsuritani, H. Shinokubo, and K. Oshima
    Org. Lett. 2002, 4, 3111-3114.

  • Efficient Pd(0)-Catalyzed Hydrosilylation of Alkynes with Triorganosilanes
    D. Motoda, H. Shinokubo, and K. Oshima
    Synlett 2002, 1529-1531.

  • Cyclization of 1,6-Enynes with Allylic Chromate Species
    T. Nishikawa, H. Shinokubo, and K. Oshima
    Org. Lett. 2002, 4, 2795-2797.

  • Reaction of α,α-Dibromo Oxime Ethers with Grignard Reagents: Alkylative Annulation Providing a Pyrimidine Core
    H. Kakiya, K. Yagi, H. Shinokubo, and K. Oshima
    J. Am. Chem. Soc. 2002, 124, 9032-9033.

  • A Room Temperature Kharasch Reaction Catalyzed by Pd(0) in a Heterogeneous Aqueous System
    D. Motoda, H. Kinoshita, H. Shinokubo, and K. Oshima
    Advanced Synthesis and Catalysis 2002, 344, 261-265.

  • Coupling of Vinylcyclopropanes with Aldehydes Induced by a TiCl4/n-Bu4NI Combination: Synthesis of Conjugated Dienols
    T. Tsuritani, H. Shinokubo, and K. Oshima
    Synlett 2002, 978-980.

  • Radical Addition of α-Halo Ester to Homoallylic Gallium or Indium Species: Formation of Cyclopropane Derivatives
    S.-I. Usugi, T. Tsuritani, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Bull. Chem. Soc. Jpn. 2002, 75, 841-845.

  • (Account) Synthetic Radical Reactions in Aqueous Media
    H. Yorimitsu, H. Shinokubo, and K. Oshima
    Synlett 2002, 674-686.

  • Pd(0)-Catalyzed Reaction of Alkynes with Trifurylgermane and CO Providing Acylgermanes: Hydrometalcarbonylation of Alkynes
    H. Kinoshita, H. Shinokubo, and K. Oshima
    J. Am. Chem. Soc. 2002, 124, 4220-4221.

  • Generation and Regioselective Reactions of α,α-Bis(silyl)-Substituted Allylcopper Reagents-Synthesis of 1,1-Disilylalkenes
    J. Kondo, A. Inoue, H. Shinokubo, and K. Oshima
    Tetrahedron Lett. 2002, 43, 2399-2402.

  • Reactions of gem-Dibromo Compounds with Trialkylmagnesate Reagents Providing Alkylated Organomagnesium Compound
    A. Inoue, J. Kondo, H. Shinokubo, and K. Oshima
    Chem. Eur. J. 2002, 8, 1730-1740.

  • Facile Synthesis of Ketones from 1,1-Disilylethenes via Oxidation of gem-Disilylalkanes
    A. Inoue, J. Kondo, H. Shinokubo, and K. Oshima
    Chem. Commun. 2002, 114-115.

  • Allylation of Carbonyl Compounds with Allylic Gallium Reagents
    T. Tsuji, S.-I. Usugi, H. Yorimitsu, H. Shinokubo, S. Matsubara, and K. Oshima
    Chem. Lett. 2002, 2-3.

2001

  • Synthesis of Trisubstituted and Tetrasubstituted Alkenes via a Manganate-Induced Migration-Elimination Process
    H. Kakita, H. Shinokubo, and K. Oshima
    Tetrahedron 2001, 57, 10063-10069.

  • Nucleophilic Addition of Tri-2-furylgermane to Aldehydes and α,β-Unsaturated Carbonyl Compounds in the Presence of a Catalytic Amount of Base
    T. Nakamura, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Tetrahedron 2001, 57, 9827-9836.

  • Conversion of Acid Chloride into Homoallylic Alcohol via Allylic C-H Bond Activation of Alkene with a Zirconocene Complex
    K. Fujita, H. Yorimitsu, H. Shinokubo, S. Matsubara, and K. Oshima
    J. Am. Chem. Soc. 2001, 123, 12115-12116.

  • Facile Synthesis of Acylsilanes via Aerobic Oxidation of gem-Disilylalkylcopper Compounds
    A. Inoue, J. Kondo, H. Shinokubo, and K. Oshima
    J. Am. Chem. Soc. 2001, 123, 11109-11110.

  • TiCl4-n-Bu4NX (X = I, Br, and Cl) Combination-Induced Coupling of α,β-Unsaturated Ketones with Aldehydes
    Z. Han, S. uehira, H. Shinokubo, and K. Oshima
    J. Org. Chem. 2001, 66, 7854-7857.

  • Triethylborane-Induced Bromine Atom-Transfer Radical Addition in Aqueous Media: Study of the Solvent Effect on Radical Addition Reaction
    H. Yorimitsu, H. Shinokubo, S. Matsubara, and K. Oshima
    J. Org. Chem. 2001, 66, 7776-7785.

  • Preparation of Organomanganese Reagents from Organic Halides with Activated Manganese
    H. Kakiya, S. Nishimae, H. Shinokubo, and K. Oshima
    Tetrahedron 2001, 57, 8807-8815.

  • Selective Oxidation of Propargylic Alcohols into α,β-Acetylenic Aldehydes with TiCl4/Et3N System
    Z. Han, H. Shinokubo, and K. Oshima
    Synlett 2001, 1421-1422.

  • A Facile Synthesis of 1,1-Disilylethenes via Me3MgLi-Induced Monomethylation of Dibromodisilylmethanes
    A. Inoue, J. Kondo, H. Shinokubo, and K. Oshima
    Chem. Lett. 2001, 956-957.

  • Radical Addition of Triphenylgermane to Vinyloxiranes: Its Application to Synthesis of 4-Vinyltetrahydro-2-furanones
    S. Tanaka, T. Nakamura, H. Yorimitsu, H. Shinokubo, S. Matsubara, and K. Oshima
    Synlett 2001, 1278-1280.

  • Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenes with a Water-Soluble Radical Initiator in Aqueous Media: Facile Synthesis of γ-Lactones
    H. Yorimitsu, K. Wakabayshi, H. Shinokubo, and K. Oshima
    Bull. Chem. Soc. Jpn. 2001, 74, 1963-1970.

  • Radical [3 + 2] Annulation of N-Allyl-N-Chlorotosylamide with Alkenes via Atom-transfer Process
    T. Tsuritani, H. Shinokubo, and K. Oshima
    Org. Lett. 2001, 3, 2709-2711.

  • Triethylborane-Induced Hydrogermylation of Alkenes with Tri-2-furylgermane
    T. Nakamura, S. Tanaka, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Computes Rendus Acad. Sci. Paris, Chimie 2001, 4, 461-470.

  • Remarkable Rate Acceleration of Pd(0)-Catalyzed Hydrogermylation of Alkynes and Dienes in Water
    H. Kinoshita, T. Nakamura, H. Kakita, H. Shinokubo, S. Matsubara, and K. Oshima
    Org. Lett. 2001, 3, 2521-2524.

  • Palladium-Catalyzed Cross-Coupling Reaction of Organoindiums with Aryl Halides in Aqueous Media
    H. Takami, H. Yorimitsu, H. Shinokubo, S. Matsubara, and K. Oshima
    Org. Lett. 2001, 3, 1997-1999.

  • Triethylborane-Induced Radical Reactions with Gallium Hydride Reagent HGaCl2
    S. Mikami, K. Fujita, T. Nakamura, H. Yorimitsu, H. Shinokubo, S. Matsubara, and K. Oshima
    Org. Lett. 2001, 3, 1853-1855.

  • Selective Halogen-Magnesium Exchange Reaction via Organomagnesium Ate Complex
    A. Inoue, K. Kitagawa, H. Shinokubo, and K. Oshima
    J. Org. Chem. 2001, 66, 4333-4339.

  • Novel [2 + 2 + 2]Annulation of 1,6-Diynes Mediated by Methallylchromate or Methallylmagnesium Chloride under CrCl Catalysis
    T. Nishikawa, H. Kakiya, H. Shinokubo, and K. Oshima
    J. Am. Chem. Soc. 2001, 123, 4629-4630.

  • Alkylative Preparation of Silylalkylmagnesium from R3SiCHBr2 Using a Magnesate Reagen
    J. Kondo, A. Inoue, H. Shinokubo, and K. Oshima
    Angew. Chem. int. Ed. 2001, 40, 2085-2087.

  • Reduction of Organic Halides with Tri-2-furylgermane: Stoichiometric and Catalytic Reduction
    T. Nakamura, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Bull. Chem. Soc. Jpn. 2001, 74, 747-752.

  • Radical Reaction by a Combination of Phosphinic Acid and a Base in Aqueous Media
    H. Yorimitsu, H. Shinokubo, and K. Oshima
    Bull. Chem. Soc. Jpn. 2001, 74, 225-235.

  • (Account) Stereospecific or Stereoselective Elimination of Vicinal-Alkoxyiodoalkanes by Means of Organometallic Reagents
    H. Shinokubo, and K. Oshima
    Synlett 2001, 322-328.

  • Iodotrimethylsilane-Induced Cyclization of 6-Alkynal Acetals
    K. Takami, H. Yorimitsu, H. Shinokubo, S. Matsubara, and K. Oshima
    Synlett 2001, 293-295.

  • Enolate Formation from Cyclopropyl Ketones via Iodide-Induced Ring Opening and Its Use for Stereoselective Aldol Reaction
    Z. Han, S. Uehira, T. Tsuritani, H. Shinokubo, and K. Oshima
    Tetrahedron 2001, 57, 987-995.

2000

  • Simple and Efficient TiCl4-Mediated Synthesis of Biaryls via Arylmagnesium Compounds
    A. Inoue, K. Kitagawa, H. Shinokubo, and K. Oshima
    Tetrahedron 2000, 56, 9601-9605.

  • Powerful Solvent Effect of Water in Radical Reaction: Triethylborane-Induced Atom-Transfer Radical Cyclization in Water
    H. Yorimitsu, T. Nakamura, H. Shinokubo, K. Oshima, and K. Omoto, and H. Fujimoto
    J. Am. Chem. Soc. 2000, 122, 11041-11047.

  • Radical Cyclization of N-Allyl-2-halo Amide in Water
    K. Wakabayashi, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Bull. Chem. Soc. Jpn. 2000, 73, 2377-2378.

  • Tributylmanganate(II)-Mediated Cyclization of Enynes
    S. Usugi, H. Shinokubo, and K. Oshima
    Bull. Chem. Soc. Jpn. 2000, 73, 1903-1904.

  • TiCl4-n-Bu4NI as a Reducing Reagent: Pinacol Coupling and Enolate Formation from α-Haloketones
    T. Tsuritani, S. Ito, H. Shinokubo, and K. Oshima
    J. Org. Chem. 2000, 65, 5066-5068.

  • A Highly Effective Aldol Reaction Mediated by Ti(O-n-Bu)4/t-BuOK Combined Reagent
    Z. Han, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Tetrahedron Lett. 2000, 41, 4415-4418.

  • Et3B-Induced Hydrogermylation of Alkenes and Silyl Enol Ethers
    H. Kakiya, H. Shinokubo, and K. Oshima
    Org. Lett. 2000, 2, 1911-1914.

  • Intramolecular Aryl Migration from Tin to Carbon via a Radical Atom-Transfer Process
    K. Wakabayashi, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Org. Lett. 2000, 2, 1899-1901.

  • Reaction of gem-Dibromocyclopropanes or Iodobenzofuran with Trialkylmanganate
    H. Kakiya, R. Inoue, H. Shinokubo, and K. Oshima
    Tetrahedron 2000, 56, 2131-2137.

  • Halogen-Magnesium Exchange via Trialkylmagnesates for the Preparation of Aryl- and Alkenylmagnesium Reagents
    K. Kitagawa, A. Inoue, H. Shinokubo, and K. Oshima
    Angew. Chem., Int. Ed. Engl. 2000, 39, 2481-2483.

  • Formation of Organomagnesium Compounds via EtMgBr-Mediated Radical Cyclization of Allyl β-Iodoacetals
    A. Inoue, H. Shinokubo, and K. Oshima
    Org. Lett. 2000, 2, 651-653.

  • Radical Cyclization Reaction Using a Combination of Phosphinic Acid and a Base in Aqueous Ethanol
    H. Yorimitsu, H. Shinokubo, and K. Oshima
    Chem. Lett. 2000, 104-105.

1999

  • An Unprecedented Coupling Reaction of Arylmagnesium Compounds with Tetrahydrofuran Providing 2-Aryltetrahydrofuran Mediated by an Iodoalkane-EtMgBr System
    A. Inoue, H. Shinokubo, and K. Oshima
    Synlett 1999, 1582-1584.

  • Highly Selective Cleavage of Prenyl Ethers by Means of a TiCl4-n-Bu4NI Mixed Reagent
    T. Tsuritani, H. Shinokubo, and K. Oshima
    Tetrahedron Lett. 1999, 40, 8121-8124.

  • Highly Stereoselective Coupling Reaction of Acrolein or Vinyl Ketone with Aldehyde
    S. Uehira, Z. Han, H. Shinokubo, and K. Oshima
    Org. Lett. 1999, 1, 1383-1385.

  • Reaction of Titanate-Type Aldehyde Enolate with Ketones to Provide 3-Hydroxyaldehydes
    K. Yachi, H. Shinokubo, and K. Oshima
    J. Am. Chem. Soc, 1999, 121, 9465-9466.

  • Preparation of Tributylstannylmanganate and its Addition to Propargylic Alcohols with High Regio- and Stereoselectivities
    T. Nakamura, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Synlett 1999, 1417-1419.

  • Reduction of Organic Halides with Tri-2-furanylgermane: Stoichiometric and Catalytic Reaction
    T. Nakamura, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Synlett 1999, 1415-1416.

  • Stereoselective Allylation of Acetals through Intramolecular Transfer of an Allylsilane
    K. Fujita, A. Inoue, H. Shinokubo, and K. Oshima
    Org. Lett. 1999, 1, 917-919.

  • Transformation of Tetrahydropyranyl Ether of Allylic Alcohol into 7-Octene-1,5-diol by Means of Trialkylmanganate
    T. Nishikawa, T. Nakamura, H. Kakiya, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Tetrahedron Lett. 1999, 40, 6613-6616.

  • A New Strategy for the Preparation of an Active Mn(0) and its Use for Radical Cyclization Reactions
    J. Tang, H. Shinokubo, and K. Oshima
    Tetrahedron 1999, 55, 1893-1904.

  • Organic Synthesis Using Organomanganese Compounds
    H. Shinokubo, and K. Oshima
    J. Synth. Org. Chem. Jpn. 1999, 57, 27-37.

  • Stereoselective Transformation of 1-Alkenyl Ether (R1CH=CHOMe) into Alkene (R1CH=CHR2) Based on Stereospecific Elimination of the Vicinal Iodo(methoxy)alkane
    A. Inoue, K. Maeda, H. Shinokubo, and K. Oshima
    Tetrahedron 1999, 55, 665-674.

  • Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenols Using a Water-Soluble Radical Initiator in Water. A Facile Synthesis of γ-Lactones
    H. Yorimistu, K. Wakabayshi, H. Shinokubo, and K. Oshima
    Tetrahedron Lett. 1999, 40, 519-522.

1998

  • Triethylborane-Induced Radical Addition of Halogenated Compounds to Alkenes and Alkynes in Water
    T. Nakamura, H. Yorimitsu, H. Shinokubo, and K. Oshima
    Synlett 1998, 1351-1352.

  • Triethylborane-Mediated Atom Transfer Radical Cyclization Reaction in Water
    H. Yorimistu, T. Nakamura, H. Shinokubo, and K. Oshima
    J. Org. Chem. 1998, 63, 8604-8605.

  • Regioselective Reaction of Dilithiated 1-Alkynylsilanol with Electrophiles
    S. Uehira, K. Takaku, H. Shinokubo, and K. Oshima
    Synlett 1998, 1096-1098.

  • New Method for the Preparation of an Active Manganese Species and its Use for Radical Cyclization Reactions
    J. Tang, H. Shinokubo, and K. Oshima
    Synlett 1998, 1075-1076.

  • Facile Generation of a Cyclopropylzinc Compound from an Alkenylzinc Derivative and Its Reaction with Electrophiles
    K. Yachi, H. Shinokubo, and K. Oshima
    Angew. Chem., Int. Ed. Engl. 1998, 37, 2515-2517.

  • Manganese(II) Chloride-Catalyzed Alkylmagnesation of 2-Alkynylphenol
    S. Nshimae, R. Inoue, H. Shinokubo, and K. Oshima
    Chem. Lett. 1998, 785-786.

  • Enolate Formation from α-Iodoaldehydes and α-Iodoketones Compounds by Means of Allylsilane-Titanium Tetrachloride and Its Application to an Aldol Reaction
    K. Maeda, H. Shinokubo, and K. Oshima
    J. Org. Chem. 1998, 63, 4558-4560.

  • Synthesis of Cyclopropanols via Cyclopropanation of Zinc Enolates
    S. Ito, H. Shinokubo, and K. Oshima
    Tetrahedron Lett. 1998, 39, 5253-5256.

  • Sequential Carbon-Carbon Bond Formation Reaction Using 1-Silyl-2-propenyllithium
    K. Takaku, H. Shinokubo, and K. Oshima
    Tetrahedron Lett. 1998, 39, 2575-2578.

  • Reaction of tert-Butyl Dibromoacetate or N,N-Diethyldibromoacetamide with Trialkylmanganate Providing an Alkylated Manganese Enolate
    R. Inoue, H. Shinokubo, and K. Oshima
    J. Org. Chem. 1998, 63, 910-911.

  • Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene. An Unprecedented Bicyclization Reaction into Bicyclo[5.3.0]decane and Bicyclo[4.3.0]nonane Skeletons
    J. Tang, H. Shinokubo, and K. Oshima
    Oragnometallics 1998, 17, 290-292.

  • Reaction of 1,3-Dihalopropene with Trialkylmanganate
    H. Kakiya, R. Inoue, H. Shinokubo, and K. Oshima
    Chem. Lett. 1998, 73-74.

  • Manganese-Catalyzed Phenylation of Acetylenic Compounds with a Phenyl Grignard Reagent
    H. Yorimistu, J. Tang, K. Okada, H. Shinokubo, and K. Oshima
    Chem. Lett. 1998, 11-12.

  • Intramolecular Radical Cyclization of 2-Haloethanal Allyl Acetal and Allyl 2-Halophenyl Ether with a Grignard Reagent in the Presence of Iron(II) Chloride
    Y. Hayashi, H. Shinokubo, and K. Oshima
    Tetrahedron Lett. 1998, 39, 63-66.

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