論文／八島栄次

Selected papers

236. A Hetero-Stranded Double helix Composed of m-Diethynylbenzene-Based Complementary molecular Strands Stabilized by Amidinium-Carboxylate Salt Bridges: Z.-Q. Wu, Y. Furusho, H. Yamada, and E. Yashima; Chem. Commun., 46, 8962-8964 (2010) DOI: 10.1039/C0CC03952G

235. Separation of C60 over C70 and Selective Extraction and Resolution of Higher Fullerenes by Syndiotactic Helical Poly(methyl methacrylate): T. Kawauchi, A. Kitaura, M. Kawauchi, T. Takeichi, J. Kumaki, H. Iida, and E. Yashima; J. Am. Chem. Soc., 132, 12191-12193 (2010) DOI: 10.1021/ja104969a

234. Helical Structure of Liquid Crystalline Poly(N-((4-n-butylphenyl)diphenylmethyl) methacrylamide): K. Nagai, K. Okoshi, S.-i. Sakurai, M. Banno, A. K. M. F. Azam, M. Kamigaito, Y. Okamoto, and E. Yashima; Macromolecules, 43, 7386-7390 (2010) DOI: 10.1021/ma1012573

233. Two-Dimensional Bilayer Smectic Ordering of Rigid Rod-Rod Helical Diblock Polyisocyanides: M. Banno, Z.-Q. Wu, K. Nagai, S.-i. Sakurai, K. Okoshi, and E. Yashima; Macromolecules, 43, 6553-6561 (2010) DOI: 10.1021/ma1009116

232. Amidinium-Carboxylate Salt Bridges as New Recognition Motif for Mechanically Interlocked Molecules: Synthesis of an Optically Active (2)Catenane and Control of Its Structure: Y. Nakatani, Y. Furusho, and E. Yashima; Angew. Chem., Int. Ed., 49, 5463-5467 (2010) DOI: DOI: 10.1002/anie.201002382
Selected as VIP Paper and highlighted in Angew. Chem., Int. Ed., 49, 8792-8794 (2010).

231. Redox-Triggered Switching of Helical Chirality of Poly(phenylacetylene)s Bearing Riboflavin Pendants: H. Iida, T. Mizoguchi, S.-D. Oh and E. Yashima; Polym. Chem., 1, 841-848 (2010) DOI: 10.1039/C0PY00044B
Selected as a Front Cover and highlighted as Hot Article

230. Complementary Double Helix Formation through Template Synthesis: H. Yamada, Y. Furusho, H. Ito, and E. Yashima; Chem. Commun., 46, 3487-3489 (2010) DOI: 10.1039/C002170A

229. Ion-Triggered Spring-like Motion of a Double Helicate Accompanied by Anisotropic Twisting: K. Miwa, Y. Furusho, and E. Yashima; Nature Chem., 2, 444-449 (2010) DOI: 10.1038/nchem.649
Selected as a Front Cover and highlighted in News and Views in Nature Chem. 2, 429-430 (2010) and Chemistry World in Royal Society of Chemistry in May 4, 2010

228. Visualization of Polymer Chain Conformations in Amorphous Polyisocyanide Langmuir-Blodgett Films by Atomic Force Microscopy: J. Kumaki, T. Kajitani, K. Nagai, K. Okoshi, and E. Yashima; J. Am. Chem. Soc., 132, 5604-5605 (2010) DOI: 10.1021/ja908426u
Highlighted in NPG Asian Materials, 7 June, 2010

226. Double-Stranded Supramolecular Assembly through Salt Bridge Formation between Rigid and Flexible Amidine and Carboxylic Acid Strands: H. Iida, M. Shimoyama, Y. Furusho, and E. Yashima; J. Org. Chem., 75, 417-423 (2010) DOI: 10.1021/jo902158v

225. Mechanism of Helix Induction in Poly(4-carboxyphenyl isocyanide) with Chiral Amines and Memory of the Macromolecular Helicity and Its Helical Structures: Y. Hase, K. Nagai, H. Iida, K. Maeda, N. Ochi, K. Sawabe, K. Sakajiri, K. Okoshi, and E. Yashima; J. Am. Chem. Soc., 131, 10719-10732 (2009) DOI: 10.1021/ja904128d

222. Double Helices with a Controlled Helicity Composed of Biphenol-Derived Phosphoric Acid Diesters: H. Yamada, K. Maeda, and E. Yashima; Chem. Eur. J., 15, 6794-6798 (2009) DOI: 10.1002/chem.200901075

221. Size-Restricted Polymerization in a Discrete Cage of Apo-Ferritin-Containing Rhodium Complexes: S. Abe, K. Hirata, T. Ueno, K. Morino, N. Shimizu, M. Yamamoto, M. Takata, E. Yashima, and Y. Watanabe; J. Am. Chem. Soc., 131, 6958-6960 (2009) DOI: 10.1021/ja901234j
Highlighted in Nature Chem., 15 May 2009.

220. Enantiomer-Selective and Helix-Sense-Selective Living Block Copolymerization of Isocyanide Enantiomers Initiated by Single-Handed Helical Poly(phenyl isocyanide)s: Z.-Q. Wu, K. Nagai, M. Banno, K. Okoshi, K. Onitsuka, and E. Yashima; J. Am. Chem. Soc., 131, 6708-6718 (2009) DOI: 10.1021/ja900036n

219. Double Helix Formation of Oligoresorcinols in Water: Thermodynamic and Kinetic Aspects: H. Goto, Y. Furusho, K. Miwa, and E. Yashima; J. Am. Chem. Soc., 131, 4710-1419 (2009) DOI: 10.1021/ja808585y

218. Helicity Induction on Water-Soluble Oligoresorcinols in Alkaline Water and Their Application to Chirality Sensing: H. Goto, Y. Furusho, and E. Yashima; Chem. Commun., 1650-1652 (2009) DOI: 10.1039/B900113A

214. Sequence-and Chain Length-Specific Complementary Double Helix Formation: H. Ito, Y. Furusho, and E. Yashima; J. Am. Chem. Soc., 130, 14008-14015 (2008) DOI: 10.1021/ja806194e
Highlighted in NPG Asia Materials (December 17, 2008)

212. Helix-Sense-Controlled Synthesis of Optically Active Poly(methyl methacrylate) Stereocomplexes: T. Kawauchi, A. Kitaura, J. Kumaki, H. Kusanagi, and E. Yashima; J. Am. Chem. Soc., 130, 11889-11891 (2008) DOI: 10.1021/ja8048805
Highlighted in NPG Asia Materials (November 25, 2008)

211. Polymerization of an Optically Active Phenylacetylene Derivative Bearing an Azide Residue by Click Reaction and with a Rhodium Catalyst: S. Kobayashi, K. Itomi, K. Morino, H. Iida, and E. Yashima; Chem. Commun., 44, 3019-3021 (2008) DOI: 10.1039/B806343E
Selected as “Hot Article”

210. Chemical Modification of a Luminescent Poly(phenylenevinylene)-Amylose Composite: K. Tamura, K. Maeda, and E. Yashima; Macromolecules, 41, 5065-5069 (2008) DOI: 10.1021/ma800811v

209. Synthesis and Helix Formation of Poly(m-phenylene)s Bearing Optically Active Oligo(ethylene oxide) Side Chains in Protic Media: T. Ben, H. Goto, K. Miwa, H. Goto, K. Morino, Y. Furusho, and E. Yashima; Macromolecules, 41, 4506-4509 (2008) DOI: 10.1021/ma800425a

208. Double-Stranded Helical Polymers Consisting of Complementary Homopolymers: T. Maeda, Y. Furusho, S.-i. Sakurai, J. Kumaki, K. Okoshi, and E. Yashima; J. Am. Chem. Soc., 130, 7938-7945 (2008) DOI: 10.1021/ja711447s
Highlighted in SYNFACTS, No. 9, 927 (2008)

204. Molecular Weight Recognition in the Multiple-Stranded Helix of a Synthetic Polymer without Specific Monomer-Monomer Interaction: J. Kumaki, T. Kawauchi, H. Kusanagi, K. Ute, T. Kitayama, and E. Yashima; J. Am. Chem. Soc., 130, 6373-6380 (2008) DOI: 10.1021/ja077861t

202. Encapsulation of Fullerenes in a Helical PMMA Cavity Leading to a Robust Processable Complex with a Macromolecular Helicity Memory: T. Kawauchi, J. Kumaki, A. Kitaura, K. Okoshi, H. Kusanagi, K. Kobayashi, T. Sugai, H. Shinohara, and E. Yashima; Angew. Chem., Int. Ed., 47, 515-519 (2008) DOI: 10.1002/anie.200703655
Highlighted in NPG Asia Materials on 24 March, 2008.

200. Two- and Three-Dimensional Smectic Ordering of Single-Handed Helical Polymers: H. Onouchi, K. Okoshi, T. Kajitani, S.-i. Sakurai, K. Nagai, K. Onitsuka, and E. Yashima; J. Am. Chem. Soc., 130, 229-236 (2008) DOI: 10.1021/ja074627u
Highlighted in SYNFACTS, No. 4, 0371 (2008).

199. Syntheses and Chiroptical Properties of Optically Active Helical Poly(phenylacetylene)s Bearing [60]Fullerene Pendants: S. Ohsawa, K. Maeda, and E. Yashima; Macromolecules, 40, 9244-9254 (2007) DOI: 10.1021/ma7022342

198. Helix Induction in Poly(phenylacetylene)s Bearing Achiral Oligoglycine Pendants by Chiral Oligopeptides in Water: K. Maeda, H. Tsukui, Y. Matsushita, and E. Yashima; Macromolecules, 40, 7721-7726 (2007) DOI: 10.1021/ma071407s

194. Two-Dimensional Helix Bundles Formation of a Dynamic Helical Poly(phenylacetylene) with Achiral Pendant Groups on Graphite: S.-i. Sakurai, S. Ohsawa, K. Nagai, K. Okoshi, J. Kumaki, and E. Yashima; Angew. Chem., Int. Ed., 46, 7605-7608 (2007) DOI: 10.1002/anie.200701546

193. Enantioselective Synthesis of Complementary Double Helical Molecules that Catalyze Asymmetric Reaction: T. Hasegawa, H. Goto, Y. Furusho, H. Katagiri, and E. Yashima; Angew. Chem., Int. Ed., 46, 5885-5888 (2007) DOI: 10.1002/anie.200701735

192. Double Helical Oligoresorcinols Recognize Oligosaccharides via Heteroduplex Formation through Noncovalent Interactions in Water: H. Goto, Y. Furusho, and E. Yashima; J. Am. Chem. Soc., 129, 9168-9174 (2007) DOI: 10.1021/ja0730359

188. Elastic Behabior of the RecA-DNA Helical Filaments: T. Nishinaka, Y. Doi, R. Hara, and E. Yashima; J. Mol. Biol., 370, 837-845 (2007) DOI: 10.1016/j.jmb.2007.05.044

187. Supramolecular Helical Assembly of an Achiral Cyanine Dye in an Induced Helical Amphiphilic Poly(phenylacetylene) Interior in Water: T. Miyagawa, M. Yamamoto, R. Muraki, H. Onouchi, and E. Yashima; J. Am. Chem. Soc., 129, 3676-3682 (2007) DOI: 10.1021/ja068951l

186. Lipase-Assisted Synthesis of an Optically Active Helical Poly(phenylacetylene) from a Racemic Phenylacetylene and the Macromolecular Helicity Inversion by Chemical Modification of the Side Groups: S. Kobayashi, K. Morino, and E. Yashima; Chem. Commun., 2351-2353 (2007) DOI: 10.1039/B701281K

185. A Supramolecular Helical Structure of the Stereocomplex Composed of Complementary Isotactic and Syndiotactic Poly(methyl methacrylate)s Revealed by Atomic Force Microscopy: J. Kumaki, T. Kawauchi, K. Okoshi, H. Kusanagi, and E. Yashima; Angew. Chem., Int. Ed., 46, 5348-5351 (2007) DOI: 10.1002/anie.200700455

184. Multicomponent Cylindrical Assemblies Driven by Amidinium-Carboxylate Salt Bridge Formation: Salt Bridge and Guest-Encapsulation Induced Helical Twist: H. Katagiri, Y. Tanaka, Y. Furusho, and E. Yashima; Angew. Chem., Int. Ed., 46, 2435-2439 (2007) DOI: 10.1002/anie.200603921

182. Unexpected Thermally Stable, Cholesteric Liquid Crystalline Helical Polyisocyanides with Macromolecular Helicity Memor: Y. Hase, Y. Mitsutsuji, M. Ishikawa, K. Maeda, K. Okoshi, and E. Yashima; Chem. Asian J., 2, 755-763 (2007) DOI: 10.1002/asia.200700051
Selected as "Cover Picture” by Editor

180. Supramolecular Control of Unwinding and Rewinding of a Double Helix of Oligoresorcinol Using Cyclodextrin/Adamantane Systeme: H. Goto, Y. Furusho, and E. Yashima; J. Am. Chem. Soc., 129, 109-112 (2007) DOI: 10.1021/ja065477a

179. Nanosphere and Nanonetwork Formations of [60]Fullerene-End-Capped Stereoregular Poly(methyl methacrylate)s through Stereocomplex Formation Combined with Self-Assembly of the Fullerenes: T. Kawauchi, J. Kumaki, and E. Yashima; J. Am. Chem. Soc., 128, 10560-10567 (2006) DOI: 10.1021/ja063252u

178. A Luminescent Poly(phenylenevinylene)－Amylose Composite with Supramolecular Liquid Crystallinity: M. Ikeda, Y. Furusho, K. Okoshi, S. Tanahara, K. Maeda, S. Nishino, T. Mori, and E. Yashima; Angew. Chem., Int. Ed., 45, 6491-6495 (2006) DOI: 10.1002/anie.200602134

177. Helicity Induction in a Poly(4-carboxyphenyl isocyanide) with Chiral Amines and Memory of the Macromolecular Helicity in Aqueous Solution: Y. Hase, M. Ishikawa, R. Muraki, K. Maeda, and E. Yashima; Macromolecules, 39, 6003-6008 (2006) DOI: 10.1021/ma0611873

173. Construction of Double-Stranded Metallosupramolecular Polymers with a Controlled Helicity by Combination of Salt Bridges and Metal Coordination: M. Ikeda, Y. Tanaka, T. Hasegawa, Y. Furusho, and E. Yashima; J. Am. Chem. Soc., 128, 6806-6807 (2006) DOI: 10.1021/ja0619096

171. Two-Dimensional Surface Chirality Control by Solvent-Induced Helicity Inversion of a Helical Polyacetylene on Graphite: S. Sakurai, K. Okoshi, J. Kumaki, and E. Yashima; J. Am. Chem. Soc., 128, 5650-565 (2006) DOI: 10.1021/ja061238b

170. Oligoresorcinols Fold into Double Helices in Water: H. Goto, H. Katagiri, Y. Furusho, and E. Yashima; J. Am. Chem. Soc., 128, 7176-7178 (2006) DOI: 10.1021/ja062171v

169. Switching of Macromolecular Helicity of Optically Active Poly(phenylacetylene)s Bearing Cyclodextrin Pendants Induced by Various External Stimuli: K. Maeda, H. Mochizuki, M. Watanabe, and E. Yashima; J. Am. Chem. Soc., 128, 7639-7650 (2006) DOI: 10.1021/ja060858+

168. Hierarchical Amplification of Macromolecular Helicity in a Lyotropic Liquid Crystalline Charged Poly(phenylacetylene) by Nonracemic Dopants in Water and Its Helical Structure: K. Nagai, K. Sakajiri, K. Maeda, K. Okoshi, T. Sato, and E. Yashima; Macromolecules, 39, 5371-5380 (2006) DOI: 10.1021/ma0606760
Selected as "Heart Cut" paper by ACS.

166. Temperature-Driven Switching of Helical Chirality of Poly[(4-carboxyphenyl)acetylene] Induced by a Single Amidine Enantiomer and Memory of the Diastereomeric Macromolecular Helicity: T. Hasegawa, K. Morino, Y. Tanaka, H. Katagiri, Y. Furusho, E. Yashima; Macromolecules, 39, 482-488 (2006) DOI: 10.1021/ma052206w

165. Assisted Formation of Chiral Porphyrin Homoaggregates by an Induced Helical Poly(phenylacetylene) Template and Their Chiral Memory: H. Onouchi, T. Miyagawa, K. Morino, and E. Yashima; Angew. Chem., Int. Ed., 45, 2381-2384 (2006) DOI: 10.1002/anie.200504162

164. Synthesis and Optical Resolution of a Double Helicate Consisting of ortho-Linked Hexaphenol Strands Bridged by Spiroborates: H. Katagiri, T. Miyagawa, Y. Furusho, and E. Yashima; Angew. Chem., Int. Ed., 46, 1741-1744 (2006) DOI: 10.1002/anie.200504326

163. Helix-Sense Controlled Polymerization of a Single Phenyl Isocyanide Enantiomer Leading to Diastereomeric Helical Polyisocyanides with Opposite Helix-Sense and Cholesteric Liquid Crystals with Opposite Twist-Sense: T. Kajitani, K. Okoshi, S. Sakurai, and E. Yashima; J. Am. Chem. Soc., 128, 708-709 (2006) DOI: 10.1021/ja0576536

157. Stereocomplex Formation of Isotactic and Syndiotactic Poly(methyl methacrylate)s in Ionic Liquids Leading to Thermoreversible Ion Gels: T. Kawauchi, J. Kumaki, K. Okoshi, and E. Yashima; Macromolecules, 38, 9155-9160 (2005) DOI: 10.1021/ma0517594

156. Two-Dimensional Hierarchical Self-Assembly of One-Handed Helical Polymers on Graphite: S. Sakurai, K. Okoshi, J. Kumaki, and E. Yashima; Angew. Chem., Int. Ed., 45, 1245-1248 (2006) DOI: 10.1002/anie.200503136

155. Layer-by-layer Assembly of Charged Poly(phenylacetylene)s with Induced Macromolecular Helicity: K. Maeda, Y. Matsushita, M. Ezaka, and E. Yashima; Chem. Commun., 4152-4154 (2005) DOI: 10.1039/B507863F
Selected as "Hot Paper" by Editor and referees

154. AFM Snapshots of Synthetic Multifunctional Pores with Polyacetylene Blockers: Pseudo-Rotaxanes and Template Effects: J. Kumaki, E. Yashima, G. Bollot, J. Mareda, S. Litvinchuk, and S. Matile; Angew. Chem., Int. Ed., 44, 6154-6157 (2005) DOI: 10.1002/anie.200501886

152. Synthesis, Isolation via Self-Assembly and Single-Molecule Observation of a [60]Fullerene-End-Capped Isotactic Poly(methyl methacrylate): T. Kawauchi, J. Kumaki, and E. Yashima; J. Am. Chem. Soc., 127, 9950-9951 (2005) DOI: 10.1021/ja052166b

150. A Modular Strategy to Artificial Double Helices: Y. Tanaka, H. Katagiri, Y. Furusho, and E. Yashima; Angew. Chem., Int. Ed., 44, 3867-3870 (2005) DOI: 10.1002/anie.200501028
Selected as VIP Paper and highlighted in Science (Editor's choice), 308, 1843 (2005).

149. Well-Defined Liquid Crystalline Properties of Rigid-Rod Helical Polyacetylenes: K. Okoshi, K. Sakajiri, J. Kumaki, and E. Yashima; Macromolecules, 38, 4061-4064 (2005) DOI: 10.1021/ma0503312

148. Conductive Metal Nanowires Produced from the Nucleoprotein Template, Complex of DNA and RecA Protein: T. Nishinaka, A. Takano, Y. Doi, M. Hashimoto, A. akamura, Y. Matsushita, J. Kumaki, and E. Yashima; J. Am. Chem. Soc., 127, 8120-8125 (2005) DOI: 10.1021/ja050487h

147. Two-Dimensional Folded Chain Crystals of a Synthetic Polymer in a Langmuir-Blodgett Film: J. Kumaki, T. Kawauchi, and E. Yashima; J. Am. Chem. Soc., 127, 5788-5789 (2005) DOI: 10.1021/ja050457e

146. Dual Memory of Enantiomeric Helices in a Polyacetylene Induced by a Single Enantiomer: T. Miyagawa, A. Furuko, K. Maeda, K. Katagiri, Y. Furusho, and E. Yashima; J. Am. Chem. Soc., 127, 5018-5019 (2005) DOI: 10.1021/ja0509634

145. Helicity Induction in a Poly(phenylacetylene) Bearing Aza-18-crown-6 Ether Pendants with Optically Active Bisamino Acids and Its Chiral Stimuli-Responsive Gelation: K. Morino, M. Oobo, and E. Yashima; Macromolecules, 38, 3461-3468 (2005) DOI: 10.1021/ma047303o

144. Enantioselective Esterification of Prochiral Phosphonate Pendants of a Polyphenylacetylene Assisted by Macromolecular Helicity: Storage of a Dynamic Macromolecular Helicity Memory: H. Onouchi, T. Miyagawa, A. Furuko, K. Maeda, and E. Yashima; J. Am. Chem. Soc., 127, 2960-2965 (2005) DOI: 10.1021/ja042806v

143. Helical Array of Pendant Fullerenes on Optically Active Poly(phenylacetylene)s: T. Nishimura, K. Maeda, S. Ohsawa, and E. Yashima; Chem. Eur. J., 11, 1181-1190 (2005) DOI: 10.1002/chem.200400812